Cocktail effect on superconductivity in hexagonal high-entropy alloys

Fuente: arXiv
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Main Authors: Liu, Bin, Yang, Wuzhang, Cao, Guang-Han, Ren, Zhi
Format: Preprint
Published: 2024
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author Liu, Bin
Yang, Wuzhang
Cao, Guang-Han
Ren, Zhi
author_facet Liu, Bin
Yang, Wuzhang
Cao, Guang-Han
Ren, Zhi
contents We report the study of the cocktail effect on superconductivity in high-entropy alloys (HEAs),using hexagonal close-packed HEAs as a prototype system. Compared with the compositional averages of the constituent elements, the superconducting transition temperature Tc is enhanced by from a factor of about 2 to over one order of magnitude. This Tc enhancement correlates with the reduction in the Debye temperature, underlining the importance of phonon softening in triggering the cocktail effect. Furthermore, we show that the Tc in these HEAs is governed by the average phonon frequency and electron-phonon coupling strength, the latter of which scales linearly with the inverse HEA molecular weight and is progressively weakened with increasing mixing entropy. Our study paves the way toward quantitative understanding of the superconductivity in HEAs.
format Preprint
id arxiv_https___arxiv_org_abs_2411_06734
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Cocktail effect on superconductivity in hexagonal high-entropy alloys
Liu, Bin
Yang, Wuzhang
Cao, Guang-Han
Ren, Zhi
Superconductivity
Materials Science
We report the study of the cocktail effect on superconductivity in high-entropy alloys (HEAs),using hexagonal close-packed HEAs as a prototype system. Compared with the compositional averages of the constituent elements, the superconducting transition temperature Tc is enhanced by from a factor of about 2 to over one order of magnitude. This Tc enhancement correlates with the reduction in the Debye temperature, underlining the importance of phonon softening in triggering the cocktail effect. Furthermore, we show that the Tc in these HEAs is governed by the average phonon frequency and electron-phonon coupling strength, the latter of which scales linearly with the inverse HEA molecular weight and is progressively weakened with increasing mixing entropy. Our study paves the way toward quantitative understanding of the superconductivity in HEAs.
title Cocktail effect on superconductivity in hexagonal high-entropy alloys
topic Superconductivity
Materials Science
url https://arxiv.org/abs/2411.06734