Micrometer-resolution fluorescence and lifetime mappings of CsPbBr$_3$ nanocrystal films coupled with a TiO$_2$ grating

Fuente: arXiv
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Main Authors: Nguyen, Viet Anh, Nguyen, Linh Thi Dieu, Do, Thi Thu Ha, Wu, Ye, Sergeev, Aleksandr A., Zhu, Ding, Valuckas, Vytautas, Pham, Duong, Bui, Hai Xuan Son, Hoang, Duy Mai, Bui, Son Tung, Bui, Xuan Khuyen, Nguyen, Binh Thanh, Nguyen, Hai Son, Vu, Lam Dinh, Rogach, Andrey, Ha, Son Tung, Le-Van, Quynh
Format: Preprint
Published: 2024
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author Nguyen, Viet Anh
Nguyen, Linh Thi Dieu
Do, Thi Thu Ha
Wu, Ye
Sergeev, Aleksandr A.
Zhu, Ding
Valuckas, Vytautas
Pham, Duong
Bui, Hai Xuan Son
Hoang, Duy Mai
Bui, Son Tung
Bui, Xuan Khuyen
Nguyen, Binh Thanh
Nguyen, Hai Son
Vu, Lam Dinh
Rogach, Andrey
Ha, Son Tung
Le-Van, Quynh
author_facet Nguyen, Viet Anh
Nguyen, Linh Thi Dieu
Do, Thi Thu Ha
Wu, Ye
Sergeev, Aleksandr A.
Zhu, Ding
Valuckas, Vytautas
Pham, Duong
Bui, Hai Xuan Son
Hoang, Duy Mai
Bui, Son Tung
Bui, Xuan Khuyen
Nguyen, Binh Thanh
Nguyen, Hai Son
Vu, Lam Dinh
Rogach, Andrey
Ha, Son Tung
Le-Van, Quynh
contents Enhancing light emission from perovskite nanocrystal (NC) films is essential in light-emitting devices, as their conventional stacks often restrict the escape of emitted light. This work addresses this challenge by employing a TiO$_2$ grating to enhance light extraction and shape the emission of CsPbBr$_3$ nanocrystal films. Angle-resolved photoluminescence (PL) demonstrated a tenfold increase in emission intensity by coupling the Bloch resonances of the grating with the spontaneous emission of the perovskite NCs. Fluorescence lifetime imaging microscopy (FLIM) provided micrometer-resolution mapping of both PL intensity and lifetime across a large area, revealing a decrease in PL lifetime from 8.2 ns for NC films on glass to 6.1 ns on the TiO$_2$ grating. Back focal plane (BFP) spectroscopy confirmed how the Bloch resonances transformed the unpolarized, spatially incoherent emission of NCs into polarized and directed light. These findings provide further insights into the interactions between dielectric nanostructures and perovskite NC films, offering possible pathways for designing better performing perovskite optoelectronic devices.
format Preprint
id arxiv_https___arxiv_org_abs_2411_12463
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Micrometer-resolution fluorescence and lifetime mappings of CsPbBr$_3$ nanocrystal films coupled with a TiO$_2$ grating
Nguyen, Viet Anh
Nguyen, Linh Thi Dieu
Do, Thi Thu Ha
Wu, Ye
Sergeev, Aleksandr A.
Zhu, Ding
Valuckas, Vytautas
Pham, Duong
Bui, Hai Xuan Son
Hoang, Duy Mai
Bui, Son Tung
Bui, Xuan Khuyen
Nguyen, Binh Thanh
Nguyen, Hai Son
Vu, Lam Dinh
Rogach, Andrey
Ha, Son Tung
Le-Van, Quynh
Optics
Applied Physics
Enhancing light emission from perovskite nanocrystal (NC) films is essential in light-emitting devices, as their conventional stacks often restrict the escape of emitted light. This work addresses this challenge by employing a TiO$_2$ grating to enhance light extraction and shape the emission of CsPbBr$_3$ nanocrystal films. Angle-resolved photoluminescence (PL) demonstrated a tenfold increase in emission intensity by coupling the Bloch resonances of the grating with the spontaneous emission of the perovskite NCs. Fluorescence lifetime imaging microscopy (FLIM) provided micrometer-resolution mapping of both PL intensity and lifetime across a large area, revealing a decrease in PL lifetime from 8.2 ns for NC films on glass to 6.1 ns on the TiO$_2$ grating. Back focal plane (BFP) spectroscopy confirmed how the Bloch resonances transformed the unpolarized, spatially incoherent emission of NCs into polarized and directed light. These findings provide further insights into the interactions between dielectric nanostructures and perovskite NC films, offering possible pathways for designing better performing perovskite optoelectronic devices.
title Micrometer-resolution fluorescence and lifetime mappings of CsPbBr$_3$ nanocrystal films coupled with a TiO$_2$ grating
topic Optics
Applied Physics
url https://arxiv.org/abs/2411.12463