Interlayer couplings in cuprates: structural origins, analytical forms, and structural estimators

Fuente: arXiv
Saved in:
Bibliographic Details
Main Authors: Jin, Zheting, Ismail-Beigi, Sohrab
Format: Preprint
Published: 2024
Subjects:
Online Access:
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1866908610438627328
author Jin, Zheting
Ismail-Beigi, Sohrab
author_facet Jin, Zheting
Ismail-Beigi, Sohrab
contents We quantitatively identify the multiple distinct microscopic mechanisms contributing to effective interlayer couplings (EICs) by performing first-principle calculations for two prototype superconducting cuprate families, pristine and doped Bi$_2$Sr$_2$CaCuO$_2$O$_{8+x}$ and Pr$_{x}$Y$_{1-x}$Ba$_2$Cu$_3$O$_7$. The major mechanisms are mediated by interlayer oxygen $p_σ$-$p_σ$ and $p_z$-$p_z$ hoppings as well as interlayer copper $d_{z^2}$-oxygen $p_σ$ hoppings. Furthermore, we show how EICs are closely related to structural distortions such as layer bucklings and bond length changes. This allows us to provide analytical formulae that permit direct estimation of the key interatomic hoppings and the EICs based only on the crystal structure. Finally, we benchmark our method on YBa$_2$Cu$_3$O$_7$ to estimate the strength and anisotropy of the EIC.
format Preprint
id arxiv_https___arxiv_org_abs_2411_18446
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Interlayer couplings in cuprates: structural origins, analytical forms, and structural estimators
Jin, Zheting
Ismail-Beigi, Sohrab
Superconductivity
We quantitatively identify the multiple distinct microscopic mechanisms contributing to effective interlayer couplings (EICs) by performing first-principle calculations for two prototype superconducting cuprate families, pristine and doped Bi$_2$Sr$_2$CaCuO$_2$O$_{8+x}$ and Pr$_{x}$Y$_{1-x}$Ba$_2$Cu$_3$O$_7$. The major mechanisms are mediated by interlayer oxygen $p_σ$-$p_σ$ and $p_z$-$p_z$ hoppings as well as interlayer copper $d_{z^2}$-oxygen $p_σ$ hoppings. Furthermore, we show how EICs are closely related to structural distortions such as layer bucklings and bond length changes. This allows us to provide analytical formulae that permit direct estimation of the key interatomic hoppings and the EICs based only on the crystal structure. Finally, we benchmark our method on YBa$_2$Cu$_3$O$_7$ to estimate the strength and anisotropy of the EIC.
title Interlayer couplings in cuprates: structural origins, analytical forms, and structural estimators
topic Superconductivity
url https://arxiv.org/abs/2411.18446