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Main Authors: Kaya, Onurcan, Gabatel, Luca, Bellani, Sebastiano, Barberis, Fabrizio, Bonaccorso, Francesco, Cole, Ivan, Roche, Stephan
Format: Preprint
Published: 2024
Subjects:
Online Access:https://arxiv.org/abs/2412.01220
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author Kaya, Onurcan
Gabatel, Luca
Bellani, Sebastiano
Barberis, Fabrizio
Bonaccorso, Francesco
Cole, Ivan
Roche, Stephan
author_facet Kaya, Onurcan
Gabatel, Luca
Bellani, Sebastiano
Barberis, Fabrizio
Bonaccorso, Francesco
Cole, Ivan
Roche, Stephan
contents The corrosion of metallic surfaces poses significant challenges across industries such as petroleum, energy, and biomedical sectors, leading to structural degradation, safety risks, and substantial maintenance costs. Traditional organic and metallic coatings provide some protection, but their limited durability and susceptibility to harsh environmental conditions necessitate the development of more advanced and efficient solutions. This has driven significant interest in two-dimensional (2D) materials, with graphene extensively studied for its exceptional mechanical strength and impermeability to gases and ions. However, while graphene offers short-term corrosion protection, its high electrical conductivity presents a long-term issue by promoting galvanic corrosion on metal surfaces. In contrast, hexagonal boron nitride (h-BN) has emerged as a promising alternative for anticorrosion coatings. h-BN combines exceptional chemical stability, impermeability, and electrical insulation, making it particularly suited for long-term protection in highly corrosive or high-temperature environments. While h-BN holds promise as anticorrosion material, challenges such as structural defects, agglomeration of nanosheets, and poor dispersion within coatings limit its performance. This review provides a comprehensive analysis of recent advancements in addressing these challenges, including novel functionalization strategies, scalable synthesis methods, and hybrid systems that integrate h-BN with complementary materials. By bridging the gap between fundamental research and industrial applications, this review outlines the potential for h-BN to revolutionize anticorrosion technologies. These obstacles necessitate advanced strategies such as surface functionalization to improve compatibility with polymer matrices and dispersion optimization to minimize agglomeration.
format Preprint
id arxiv_https___arxiv_org_abs_2412_01220
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle 2D Hexagonal Boron Nitride-based Anticorrosion Coatings
Kaya, Onurcan
Gabatel, Luca
Bellani, Sebastiano
Barberis, Fabrizio
Bonaccorso, Francesco
Cole, Ivan
Roche, Stephan
Materials Science
The corrosion of metallic surfaces poses significant challenges across industries such as petroleum, energy, and biomedical sectors, leading to structural degradation, safety risks, and substantial maintenance costs. Traditional organic and metallic coatings provide some protection, but their limited durability and susceptibility to harsh environmental conditions necessitate the development of more advanced and efficient solutions. This has driven significant interest in two-dimensional (2D) materials, with graphene extensively studied for its exceptional mechanical strength and impermeability to gases and ions. However, while graphene offers short-term corrosion protection, its high electrical conductivity presents a long-term issue by promoting galvanic corrosion on metal surfaces. In contrast, hexagonal boron nitride (h-BN) has emerged as a promising alternative for anticorrosion coatings. h-BN combines exceptional chemical stability, impermeability, and electrical insulation, making it particularly suited for long-term protection in highly corrosive or high-temperature environments. While h-BN holds promise as anticorrosion material, challenges such as structural defects, agglomeration of nanosheets, and poor dispersion within coatings limit its performance. This review provides a comprehensive analysis of recent advancements in addressing these challenges, including novel functionalization strategies, scalable synthesis methods, and hybrid systems that integrate h-BN with complementary materials. By bridging the gap between fundamental research and industrial applications, this review outlines the potential for h-BN to revolutionize anticorrosion technologies. These obstacles necessitate advanced strategies such as surface functionalization to improve compatibility with polymer matrices and dispersion optimization to minimize agglomeration.
title 2D Hexagonal Boron Nitride-based Anticorrosion Coatings
topic Materials Science
url https://arxiv.org/abs/2412.01220