The Role of Defect Geometry in Localized Emission from Monolayer Tungsten Dichalcogenides
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arXiv
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| Main Authors: | , , , , , , , , , , , , |
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| Format: | Preprint |
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2024
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| _version_ | 1866910056624160768 |
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| author | Gavin, S. Carin Kar, Moumita Wen, Jianguo Dasgupta, Anushka Pei, Jinxuan Liu, Yiying Zhang, Boyu Zeman IV, Charles J. Heremans, F. Joseph Marks, Tobin J. Hersam, Mark C. Schatz, George C. Stern, Nathaniel P. |
| author_facet | Gavin, S. Carin Kar, Moumita Wen, Jianguo Dasgupta, Anushka Pei, Jinxuan Liu, Yiying Zhang, Boyu Zeman IV, Charles J. Heremans, F. Joseph Marks, Tobin J. Hersam, Mark C. Schatz, George C. Stern, Nathaniel P. |
| contents | Understanding the mechanism of single photon emission (SPE) in two-dimensional (2D) material is an unsolved problem important for quantum optical materials and the development of quantum information applications. In 2D transition metal dichalcogenides (TMDs) such as tungsten diselenide (WSe2), quantum emission has been broadly attributed to exciton localization from atomic point defects, yet the precise microscopic origins are not fully understood. This work introduces an empirically grounded computational framework that explains both the origins of facile SPE in WSe2 and its relative scarcity in related TMD, tungsten disulfide. High resolution microscopy identifies native defect geometries existing in monolayer WSe2 lattices providing the ingredients necessary to build a realistic model. The qualitative effects of chalcogen type, defect geometry, and mechanical strain on the electronic structure are then individually assessed using density functional theory, from which a specific divacancy configuration emerges as the candidate for localized single-electron transitions that match observed spectral energies. Spectroscopy and photon correlation measurements further validate this model, establishing a self-consistent link between defect geometry, electronic structure, and quantum emission. By isolating the distinct roles of chalcogen type, defect configuration, and mechanical strain, this work provides a thorough investigation of exciton localization and optical behavior, contributing to a clearer picture of the physical drivers of single photon emission in tungsten-based TMDs. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2412_03686 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | The Role of Defect Geometry in Localized Emission from Monolayer Tungsten Dichalcogenides Gavin, S. Carin Kar, Moumita Wen, Jianguo Dasgupta, Anushka Pei, Jinxuan Liu, Yiying Zhang, Boyu Zeman IV, Charles J. Heremans, F. Joseph Marks, Tobin J. Hersam, Mark C. Schatz, George C. Stern, Nathaniel P. Materials Science Understanding the mechanism of single photon emission (SPE) in two-dimensional (2D) material is an unsolved problem important for quantum optical materials and the development of quantum information applications. In 2D transition metal dichalcogenides (TMDs) such as tungsten diselenide (WSe2), quantum emission has been broadly attributed to exciton localization from atomic point defects, yet the precise microscopic origins are not fully understood. This work introduces an empirically grounded computational framework that explains both the origins of facile SPE in WSe2 and its relative scarcity in related TMD, tungsten disulfide. High resolution microscopy identifies native defect geometries existing in monolayer WSe2 lattices providing the ingredients necessary to build a realistic model. The qualitative effects of chalcogen type, defect geometry, and mechanical strain on the electronic structure are then individually assessed using density functional theory, from which a specific divacancy configuration emerges as the candidate for localized single-electron transitions that match observed spectral energies. Spectroscopy and photon correlation measurements further validate this model, establishing a self-consistent link between defect geometry, electronic structure, and quantum emission. By isolating the distinct roles of chalcogen type, defect configuration, and mechanical strain, this work provides a thorough investigation of exciton localization and optical behavior, contributing to a clearer picture of the physical drivers of single photon emission in tungsten-based TMDs. |
| title | The Role of Defect Geometry in Localized Emission from Monolayer Tungsten Dichalcogenides |
| topic | Materials Science |
| url | https://arxiv.org/abs/2412.03686 |