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| Main Authors: | , , , , , , , , |
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| Format: | Preprint |
| Published: |
2024
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2412.08986 |
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| _version_ | 1866909677969735680 |
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| author | Lam, Leo S. I. Deng, Hai-Yao Zhang, Wei-Bing Nwankwo, Udoka Xiao, Chu Yip, Cho-Tung Lee, Chun-Shing Ruan, Haihui Lam, Chi-Hang |
| author_facet | Lam, Leo S. I. Deng, Hai-Yao Zhang, Wei-Bing Nwankwo, Udoka Xiao, Chu Yip, Cho-Tung Lee, Chun-Shing Ruan, Haihui Lam, Chi-Hang |
| contents | The physics of glass has been a significant topic of interest for decades. Dynamical facilitation is widely believed to be an important characteristic of glassy dynamics, but the precise mechanism is still under debate. We propose a lattice model of glass called the facilitated random walk (FRW). Each particle performs continuous time random walk in the presence of its own random local kinetic constraints. The particles do not interact energetically. Instead, they interact kinetically with a hopping rate resampling rule under which motions of a particle can randomly perturb the local kinetic constraints of other particles. This dynamic interaction is reversible, following a rate restoration rule. A step-by-step reversal of the particle motions exactly restore the previous constraints, modeling randomness quenched in the configuration space of glass. The model exhibits stretched exponential relaxation and dynamical heterogeneity typical of glasses. Despite the lack of explicit facilitation rule, the FRW shows facilitation behaviors closely analogous to those of the kinetically constrained models (KCM). The FRW is a coarse-grained version of the distinguishable particle lattice model (DPLM) and this exemplifies that compatible defect and atomistic models can complement each other on the study of glass. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2412_08986 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Emergent facilitation by random constraints in a facilitated random walk model of glass Lam, Leo S. I. Deng, Hai-Yao Zhang, Wei-Bing Nwankwo, Udoka Xiao, Chu Yip, Cho-Tung Lee, Chun-Shing Ruan, Haihui Lam, Chi-Hang Statistical Mechanics The physics of glass has been a significant topic of interest for decades. Dynamical facilitation is widely believed to be an important characteristic of glassy dynamics, but the precise mechanism is still under debate. We propose a lattice model of glass called the facilitated random walk (FRW). Each particle performs continuous time random walk in the presence of its own random local kinetic constraints. The particles do not interact energetically. Instead, they interact kinetically with a hopping rate resampling rule under which motions of a particle can randomly perturb the local kinetic constraints of other particles. This dynamic interaction is reversible, following a rate restoration rule. A step-by-step reversal of the particle motions exactly restore the previous constraints, modeling randomness quenched in the configuration space of glass. The model exhibits stretched exponential relaxation and dynamical heterogeneity typical of glasses. Despite the lack of explicit facilitation rule, the FRW shows facilitation behaviors closely analogous to those of the kinetically constrained models (KCM). The FRW is a coarse-grained version of the distinguishable particle lattice model (DPLM) and this exemplifies that compatible defect and atomistic models can complement each other on the study of glass. |
| title | Emergent facilitation by random constraints in a facilitated random walk model of glass |
| topic | Statistical Mechanics |
| url | https://arxiv.org/abs/2412.08986 |