Radiator Tailoring for Enhanced Performance in InAs-Based Near-Field Thermophotovoltaics

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Main Authors: Giroux, Mathieu, Molesky, Sean, St-Gelais, Raphael, Krich, Jacob J.
Format: Preprint
Published: 2024
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author Giroux, Mathieu
Molesky, Sean
St-Gelais, Raphael
Krich, Jacob J.
author_facet Giroux, Mathieu
Molesky, Sean
St-Gelais, Raphael
Krich, Jacob J.
contents Near-field thermophotovoltaics (NFTPV) systems have significant potential for waste heat recovery applications, with both high theoretical efficiency and power density, up to 40% and $11 \ \mathrm{W/cm^{2}}$ at 900 K. Yet experimental demonstrations have only achieved up to 14% efficiency and modest power densities (i.e., $0.75 \ \mathrm{W/cm^{2}}$). While experiments have recently started to focus on photovoltaic (PV) cells custom-made for NFTPV, most work still relies on conventional doped silicon radiators. In this work, we design an optimized NFTPV radiator for an indium arsenide-based system and, in the process, investigate models for the permittivity of InAs in the context of NFTPV. Based on existing measurements of InAs absorption, we find that the traditional Drude model overestimates free carrier absorption in InAs. We replace the Drude portion of the InAs dielectric function with a revised model derived from ionized impurity scattering. Using this revised model, we maximize the spectral efficiency and power density of a NFTPV system by optimizing the spectral coupling between a radiator and an InAs PV cell. We find that when the radiator and the PV cell are both made of InAs, a nearly threefold improvement of spectral efficiency is possible compared to a traditional silicon radiator with the same InAs cell. This enhancement reduces subgap thermal transfer while maintaining power output.
format Preprint
id arxiv_https___arxiv_org_abs_2412_10217
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Radiator Tailoring for Enhanced Performance in InAs-Based Near-Field Thermophotovoltaics
Giroux, Mathieu
Molesky, Sean
St-Gelais, Raphael
Krich, Jacob J.
Applied Physics
Near-field thermophotovoltaics (NFTPV) systems have significant potential for waste heat recovery applications, with both high theoretical efficiency and power density, up to 40% and $11 \ \mathrm{W/cm^{2}}$ at 900 K. Yet experimental demonstrations have only achieved up to 14% efficiency and modest power densities (i.e., $0.75 \ \mathrm{W/cm^{2}}$). While experiments have recently started to focus on photovoltaic (PV) cells custom-made for NFTPV, most work still relies on conventional doped silicon radiators. In this work, we design an optimized NFTPV radiator for an indium arsenide-based system and, in the process, investigate models for the permittivity of InAs in the context of NFTPV. Based on existing measurements of InAs absorption, we find that the traditional Drude model overestimates free carrier absorption in InAs. We replace the Drude portion of the InAs dielectric function with a revised model derived from ionized impurity scattering. Using this revised model, we maximize the spectral efficiency and power density of a NFTPV system by optimizing the spectral coupling between a radiator and an InAs PV cell. We find that when the radiator and the PV cell are both made of InAs, a nearly threefold improvement of spectral efficiency is possible compared to a traditional silicon radiator with the same InAs cell. This enhancement reduces subgap thermal transfer while maintaining power output.
title Radiator Tailoring for Enhanced Performance in InAs-Based Near-Field Thermophotovoltaics
topic Applied Physics
url https://arxiv.org/abs/2412.10217