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Auteurs principaux: Hatt, Sabrina R., Shaw, Camille, Zappala, Emma, Baral, Raju, Calder, Stuart, Morris, Gerald D., Ortiz, Brenden R., Chesnel, Karine, Frandsen, Benjamin A.
Format: Preprint
Publié: 2024
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Accès en ligne:https://arxiv.org/abs/2412.16130
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author Hatt, Sabrina R.
Shaw, Camille
Zappala, Emma
Baral, Raju
Calder, Stuart
Morris, Gerald D.
Ortiz, Brenden R.
Chesnel, Karine
Frandsen, Benjamin A.
author_facet Hatt, Sabrina R.
Shaw, Camille
Zappala, Emma
Baral, Raju
Calder, Stuart
Morris, Gerald D.
Ortiz, Brenden R.
Chesnel, Karine
Frandsen, Benjamin A.
contents We present a magnetometry, muon spin relaxation ($μ$SR), and neutron scattering study of the insulating face-centered-cubic spin glass Zn$_{0.5}$Mn$_{0.5}$Te. The magnetometry and $μ$SR results confirm a spin freezing transition around $T_f \approx 23$ K, with the spin fluctuation rate decreasing gradually and somewhat inhomogeneously through the sample volume as the temperature decreases toward $T_f$. Characteristic spin correlation times well above $T_f$ are on the order of 10$^{-10}$ s, in line with expectations for a cluster spin glass. Using magnetic pair distribution function (mPDF) analysis and reverse Monte Carlo (RMC) modeling of the magnetic diffuse neutron scattering data, we show that the spin-glass ground state consists of clusters of spins exhibiting short-range-ordered type-III antiferromagnetic correlations, with a locally ordered moment of 3.1(1) $μ_{\mathrm{B}}$ between nearest-neighbor spins. The type-III correlations decay exponentially as a function of spin separation distance with a correlation length of approximately 5 Å. The diffuse magnetic scattering and corresponding mPDF show no significant changes across $T_f$, indicating that the dynamically fluctuating short-range spin correlations in the paramagnetic state retain the same basic type-III configuration; the only change apparent from the neutron scattering data is a gradual reduction of the correlation length and locally ordered moment with increasing temperature. Taken together, these results paint a unique and detailed picture of the local magnetic structure and dynamics in Zn$_{0.5}$Mn$_{0.5}$Te and show that this material is best described as a cluster spin glass. In addition, this work showcases a statistical method for extracting diffuse scattering signals from neutron powder diffraction data.
format Preprint
id arxiv_https___arxiv_org_abs_2412_16130
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Cluster spin glass correlations and dynamics in Zn$_{0.5}$Mn$_{0.5}$Te
Hatt, Sabrina R.
Shaw, Camille
Zappala, Emma
Baral, Raju
Calder, Stuart
Morris, Gerald D.
Ortiz, Brenden R.
Chesnel, Karine
Frandsen, Benjamin A.
Materials Science
We present a magnetometry, muon spin relaxation ($μ$SR), and neutron scattering study of the insulating face-centered-cubic spin glass Zn$_{0.5}$Mn$_{0.5}$Te. The magnetometry and $μ$SR results confirm a spin freezing transition around $T_f \approx 23$ K, with the spin fluctuation rate decreasing gradually and somewhat inhomogeneously through the sample volume as the temperature decreases toward $T_f$. Characteristic spin correlation times well above $T_f$ are on the order of 10$^{-10}$ s, in line with expectations for a cluster spin glass. Using magnetic pair distribution function (mPDF) analysis and reverse Monte Carlo (RMC) modeling of the magnetic diffuse neutron scattering data, we show that the spin-glass ground state consists of clusters of spins exhibiting short-range-ordered type-III antiferromagnetic correlations, with a locally ordered moment of 3.1(1) $μ_{\mathrm{B}}$ between nearest-neighbor spins. The type-III correlations decay exponentially as a function of spin separation distance with a correlation length of approximately 5 Å. The diffuse magnetic scattering and corresponding mPDF show no significant changes across $T_f$, indicating that the dynamically fluctuating short-range spin correlations in the paramagnetic state retain the same basic type-III configuration; the only change apparent from the neutron scattering data is a gradual reduction of the correlation length and locally ordered moment with increasing temperature. Taken together, these results paint a unique and detailed picture of the local magnetic structure and dynamics in Zn$_{0.5}$Mn$_{0.5}$Te and show that this material is best described as a cluster spin glass. In addition, this work showcases a statistical method for extracting diffuse scattering signals from neutron powder diffraction data.
title Cluster spin glass correlations and dynamics in Zn$_{0.5}$Mn$_{0.5}$Te
topic Materials Science
url https://arxiv.org/abs/2412.16130