Attosecond All-Optical Retrieval of Valley Polarization via Circular Dichroism in Transient Absorption

Fuente: arXiv
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Main Authors: Li, Wenqing, Zhu, Xiaosong, Lan, Pengfei, Wang, Kai, He, Wanzhu, Hübener, Hannes, De Giovannini, Umberto, Lu, Peixiang
Format: Preprint
Published: 2024
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author Li, Wenqing
Zhu, Xiaosong
Lan, Pengfei
Wang, Kai
He, Wanzhu
Hübener, Hannes
De Giovannini, Umberto
Lu, Peixiang
author_facet Li, Wenqing
Zhu, Xiaosong
Lan, Pengfei
Wang, Kai
He, Wanzhu
Hübener, Hannes
De Giovannini, Umberto
Lu, Peixiang
contents We propose a scheme for retrieving the ultrafast valley polarization (VP) dynamics in two-dimensional hexagonal materials via attosecond circular dichroism (CD) transient absorption spectroscopy. This approach builds on the CD transition between the first and higher conduction bands induced by the circularly polarized probe pulses. The population imbalance at nonequivalent valleys in the first conduction band is proportionally mapped onto the difference in absorption coefficients of two probe pulses with opposite helicities, supporting an unprecedented quantitative retrieval of the corresponding VP dynamics with subfemtosecond time resolution. We theoretically demonstrate the scheme for h-BN and MoS2 through ab initio calculations, achieving an accurate retrieval of the VP dynamics, particularly the transient VP switching processes, with a time resolution of 250 as.
format Preprint
id arxiv_https___arxiv_org_abs_2412_19612
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Attosecond All-Optical Retrieval of Valley Polarization via Circular Dichroism in Transient Absorption
Li, Wenqing
Zhu, Xiaosong
Lan, Pengfei
Wang, Kai
He, Wanzhu
Hübener, Hannes
De Giovannini, Umberto
Lu, Peixiang
Optics
We propose a scheme for retrieving the ultrafast valley polarization (VP) dynamics in two-dimensional hexagonal materials via attosecond circular dichroism (CD) transient absorption spectroscopy. This approach builds on the CD transition between the first and higher conduction bands induced by the circularly polarized probe pulses. The population imbalance at nonequivalent valleys in the first conduction band is proportionally mapped onto the difference in absorption coefficients of two probe pulses with opposite helicities, supporting an unprecedented quantitative retrieval of the corresponding VP dynamics with subfemtosecond time resolution. We theoretically demonstrate the scheme for h-BN and MoS2 through ab initio calculations, achieving an accurate retrieval of the VP dynamics, particularly the transient VP switching processes, with a time resolution of 250 as.
title Attosecond All-Optical Retrieval of Valley Polarization via Circular Dichroism in Transient Absorption
topic Optics
url https://arxiv.org/abs/2412.19612