Machine learning orbital-free density functional theory: taming quantum shell effects in deformed nuclei

Fuente: arXiv
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Auteurs principaux: Wu, X. H., Ren, Z. X., Zhao, P. W.
Format: Preprint
Publié: 2024
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author Wu, X. H.
Ren, Z. X.
Zhao, P. W.
author_facet Wu, X. H.
Ren, Z. X.
Zhao, P. W.
contents Accurate description of deformed atomic nuclei by the orbital-free density functional theory has been a longstanding textbook challenge, due to the difficulty in accounting for the intricate quantum shell effects that are present in such systems. Orbital-free density functional theory is, in principle, capable of describing all effects of nuclear systems, as guaranteed by the Hohenberg-Kohn theorem. However, from a microscopic perspective, shell and deformation effects are believed to be intrinsically connected to single-orbital structures, posing a significant challenge for orbital-free approaches. Here, we develop a machine learning approach to the orbital-free density functional theory, which is capable of achieving a high level of accuracy in describing the ground-state properties and potential energy curves for both spherical $^{16}$O and deformed $^{20}$Ne nuclei. This is the inaugural instance where a fully orbital-free energy density functional has succeeded in taming the complex shell effects in deformed nuclei. It demonstrates that the orbital-free energy density functional, which is directly based on the Hohenberg-Kohn theorem, is not only a theoretical concept but also a practical one for nuclear systems.
format Preprint
id arxiv_https___arxiv_org_abs_2412_20739
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Machine learning orbital-free density functional theory: taming quantum shell effects in deformed nuclei
Wu, X. H.
Ren, Z. X.
Zhao, P. W.
Nuclear Theory
Nuclear Experiment
Quantum Physics
Accurate description of deformed atomic nuclei by the orbital-free density functional theory has been a longstanding textbook challenge, due to the difficulty in accounting for the intricate quantum shell effects that are present in such systems. Orbital-free density functional theory is, in principle, capable of describing all effects of nuclear systems, as guaranteed by the Hohenberg-Kohn theorem. However, from a microscopic perspective, shell and deformation effects are believed to be intrinsically connected to single-orbital structures, posing a significant challenge for orbital-free approaches. Here, we develop a machine learning approach to the orbital-free density functional theory, which is capable of achieving a high level of accuracy in describing the ground-state properties and potential energy curves for both spherical $^{16}$O and deformed $^{20}$Ne nuclei. This is the inaugural instance where a fully orbital-free energy density functional has succeeded in taming the complex shell effects in deformed nuclei. It demonstrates that the orbital-free energy density functional, which is directly based on the Hohenberg-Kohn theorem, is not only a theoretical concept but also a practical one for nuclear systems.
title Machine learning orbital-free density functional theory: taming quantum shell effects in deformed nuclei
topic Nuclear Theory
Nuclear Experiment
Quantum Physics
url https://arxiv.org/abs/2412.20739