Unveiling potential candidates for rare-earth-free permanent magnet and magnetocaloric effect applications: a high throughput screening in Fe-N alloys

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Autori principali: Gao, Qiang, Bao, Ergen, Shahid, Ijaz, Ma, Hui, Chen, Xing-Qiu
Natura: Preprint
Pubblicazione: 2025
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author Gao, Qiang
Bao, Ergen
Shahid, Ijaz
Ma, Hui
Chen, Xing-Qiu
author_facet Gao, Qiang
Bao, Ergen
Shahid, Ijaz
Ma, Hui
Chen, Xing-Qiu
contents Based on high-throughput density functional theory calculations, we have found 49 ferromag-netic cases in FexN1-x (0<x<1) compounds, focusing especially on permanent magnet and giant magnetocaloric effect applications. It is found that 15 compounds are potential permanent mag-nets with a magneto-crystalline anisotropy energy more than 1 MJ/m3, filling in the gap of appli-cation spectrum between high-performance and widely used permanents. Among the potential permanent magnets, Fe2N can be classified as a hard magnet while the other 14 compounds can be classified as semi-hard magnets. According to the calculations of magnetic deformation proxy, 40 compounds are identified as potential giant magnetocaloric effect candidates. We suspect that Fe-N compounds provide fine opportunities for applications in both rare-earth free permanent magnets and magnetocaloric effect.
format Preprint
id arxiv_https___arxiv_org_abs_2501_01607
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Unveiling potential candidates for rare-earth-free permanent magnet and magnetocaloric effect applications: a high throughput screening in Fe-N alloys
Gao, Qiang
Bao, Ergen
Shahid, Ijaz
Ma, Hui
Chen, Xing-Qiu
Materials Science
Based on high-throughput density functional theory calculations, we have found 49 ferromag-netic cases in FexN1-x (0<x<1) compounds, focusing especially on permanent magnet and giant magnetocaloric effect applications. It is found that 15 compounds are potential permanent mag-nets with a magneto-crystalline anisotropy energy more than 1 MJ/m3, filling in the gap of appli-cation spectrum between high-performance and widely used permanents. Among the potential permanent magnets, Fe2N can be classified as a hard magnet while the other 14 compounds can be classified as semi-hard magnets. According to the calculations of magnetic deformation proxy, 40 compounds are identified as potential giant magnetocaloric effect candidates. We suspect that Fe-N compounds provide fine opportunities for applications in both rare-earth free permanent magnets and magnetocaloric effect.
title Unveiling potential candidates for rare-earth-free permanent magnet and magnetocaloric effect applications: a high throughput screening in Fe-N alloys
topic Materials Science
url https://arxiv.org/abs/2501.01607