Identification of the interstellar 1-cyano propargyl radical (HCCCHCN) in TMC-1

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Auteurs principaux: Cabezas, C., Agúndez, M., Marcelino, N., Chang, C. H., Fuentetaja, R., Tercero, B., Nakajima, M., Endo, Y., de Vicente, P., Cernicharo, J.
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Publié: 2025
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author Cabezas, C.
Agúndez, M.
Marcelino, N.
Chang, C. H.
Fuentetaja, R.
Tercero, B.
Nakajima, M.
Endo, Y.
de Vicente, P.
Cernicharo, J.
author_facet Cabezas, C.
Agúndez, M.
Marcelino, N.
Chang, C. H.
Fuentetaja, R.
Tercero, B.
Nakajima, M.
Endo, Y.
de Vicente, P.
Cernicharo, J.
contents We report the first detection in interstellar medium of the 1-cyano propargyl radical, HC$_3$HCN. This species is an isomer of the 3-cyano propargyl radical (CH$_2$C$_3$N), which was recently discovered in TMC-1. The 1-cyano propargyl radical was observed in the cold dark cloud TMC-1 using data from the ongoing QUIJOTE line survey, which is being carried out with the Yebes 40m telescope. A total of seven rotational transitions with multiple hyperfine components were detected in the 31.0-50.4 GHz range. We derived a column density of (2.2$\pm$0.2)$\times$10$^{11}$ cm$^{-2}$ and a rotational temperature of 7$\pm$1\,K. The abundance ratio between HC$_3$HCN and CH$_2$C$_3$N is 1.4. The almost equal abundance of these isomers indicates that the two species may be produced in the same reaction with a similar efficiency, probably in the reaction C + CH$_2$CHCN and perhaps also in the reaction C$_2$ + CH$_3$CN and the dissociative recombination with electrons of CH$_2$C$_3$NH$^+$
format Preprint
id arxiv_https___arxiv_org_abs_2501_01938
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Identification of the interstellar 1-cyano propargyl radical (HCCCHCN) in TMC-1
Cabezas, C.
Agúndez, M.
Marcelino, N.
Chang, C. H.
Fuentetaja, R.
Tercero, B.
Nakajima, M.
Endo, Y.
de Vicente, P.
Cernicharo, J.
Astrophysics of Galaxies
We report the first detection in interstellar medium of the 1-cyano propargyl radical, HC$_3$HCN. This species is an isomer of the 3-cyano propargyl radical (CH$_2$C$_3$N), which was recently discovered in TMC-1. The 1-cyano propargyl radical was observed in the cold dark cloud TMC-1 using data from the ongoing QUIJOTE line survey, which is being carried out with the Yebes 40m telescope. A total of seven rotational transitions with multiple hyperfine components were detected in the 31.0-50.4 GHz range. We derived a column density of (2.2$\pm$0.2)$\times$10$^{11}$ cm$^{-2}$ and a rotational temperature of 7$\pm$1\,K. The abundance ratio between HC$_3$HCN and CH$_2$C$_3$N is 1.4. The almost equal abundance of these isomers indicates that the two species may be produced in the same reaction with a similar efficiency, probably in the reaction C + CH$_2$CHCN and perhaps also in the reaction C$_2$ + CH$_3$CN and the dissociative recombination with electrons of CH$_2$C$_3$NH$^+$
title Identification of the interstellar 1-cyano propargyl radical (HCCCHCN) in TMC-1
topic Astrophysics of Galaxies
url https://arxiv.org/abs/2501.01938