Large upper critical fields and strong coupling superconductivity in the medium-entropy alloy (Ti1/3Hf1/3Ta1/3)1-xNbx

Fuente: arXiv
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Autori principali: Li, Longfu, Tian, Hongyan, Hu, Xunwu, Zeng, Lingyong, Li, Kuan, Yu, Peifeng, Wang, Kangwang, Chen, Rui, Xiang, Zaichen, Yao, Dao-Xin, Luo, Huixia
Natura: Preprint
Pubblicazione: 2025
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author Li, Longfu
Tian, Hongyan
Hu, Xunwu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Chen, Rui
Xiang, Zaichen
Yao, Dao-Xin
Luo, Huixia
author_facet Li, Longfu
Tian, Hongyan
Hu, Xunwu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Chen, Rui
Xiang, Zaichen
Yao, Dao-Xin
Luo, Huixia
contents Since the discovery of high-entropy superconductors in 2014, superconductivity has remained a focal point of interest in medium- and high-entropy alloys (MEAs-HEAs). Here, we report a series of (Ti0.33Hf0.33Ta0.33)1-xNbx MEA superconductors crystallized in the BCC structure, whose superconductivity was characterized by resistivity, magnetization, and specific heat measurements. The study found that the (Ti0.33Hf0.33Ta0.33)1-xNbx MEAs exhibit bulk superconductivity. With the doping of Nb, the superconducting transition temperature (Tc) increases from 5.31 K to 9.11 K, and the normalized Cel jumps at Tc, and the logarithmically averaged characteristic phonon frequency exhibit dome-shaped curves. Results from specific heat measurements indicate that the superconductivity is of a strongly coupled s-wave type observed. Furthermore, at low Nb content, the upper critical field of the samples is larger than the Pauli paramagnetic limit. The strongly coupling behavior and large upper critical field in s-wave type (Ti0.33Hf0.33Ta0.33)1-xNbx MEA superconductors are unusual, as they typically occur in other unconventional superconductors. Thus, (Ti0.33Hf0.33Ta0.33)1-xNbx may have significant potential in the research and understanding of physical mechanisms.
format Preprint
id arxiv_https___arxiv_org_abs_2501_02455
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Large upper critical fields and strong coupling superconductivity in the medium-entropy alloy (Ti1/3Hf1/3Ta1/3)1-xNbx
Li, Longfu
Tian, Hongyan
Hu, Xunwu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Chen, Rui
Xiang, Zaichen
Yao, Dao-Xin
Luo, Huixia
Superconductivity
Since the discovery of high-entropy superconductors in 2014, superconductivity has remained a focal point of interest in medium- and high-entropy alloys (MEAs-HEAs). Here, we report a series of (Ti0.33Hf0.33Ta0.33)1-xNbx MEA superconductors crystallized in the BCC structure, whose superconductivity was characterized by resistivity, magnetization, and specific heat measurements. The study found that the (Ti0.33Hf0.33Ta0.33)1-xNbx MEAs exhibit bulk superconductivity. With the doping of Nb, the superconducting transition temperature (Tc) increases from 5.31 K to 9.11 K, and the normalized Cel jumps at Tc, and the logarithmically averaged characteristic phonon frequency exhibit dome-shaped curves. Results from specific heat measurements indicate that the superconductivity is of a strongly coupled s-wave type observed. Furthermore, at low Nb content, the upper critical field of the samples is larger than the Pauli paramagnetic limit. The strongly coupling behavior and large upper critical field in s-wave type (Ti0.33Hf0.33Ta0.33)1-xNbx MEA superconductors are unusual, as they typically occur in other unconventional superconductors. Thus, (Ti0.33Hf0.33Ta0.33)1-xNbx may have significant potential in the research and understanding of physical mechanisms.
title Large upper critical fields and strong coupling superconductivity in the medium-entropy alloy (Ti1/3Hf1/3Ta1/3)1-xNbx
topic Superconductivity
url https://arxiv.org/abs/2501.02455