On the abiotic origin of dimethyl sulfide: discovery of DMS in the Interstellar Medium
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| Autores principales: | , , , , , , , , , , , , , , , , |
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| Formato: | Preprint |
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2025
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| author | Sanz-Novo, Miguel Rivilla, Víctor M. Endres, Christian P. Lattanzi, Valerio Jiménez-Serra, Izaskun Colzi, Laura Zeng, Shaoshan Megías, Andrés López-Gallifa, Álvaro Martínez-Henares, Antonio Andrés, David San Tercero, Belén de Vicente, Pablo Martín, Sergio Requena-Torres, Miguel A. Caselli, Paola Martín-Pintado, Jesús |
| author_facet | Sanz-Novo, Miguel Rivilla, Víctor M. Endres, Christian P. Lattanzi, Valerio Jiménez-Serra, Izaskun Colzi, Laura Zeng, Shaoshan Megías, Andrés López-Gallifa, Álvaro Martínez-Henares, Antonio Andrés, David San Tercero, Belén de Vicente, Pablo Martín, Sergio Requena-Torres, Miguel A. Caselli, Paola Martín-Pintado, Jesús |
| contents | Following the discovery of dimethyl sulfide (CH$_3$SCH$_3$, DMS) signatures in comet 67P/Churyumov-Gerasimenko, we report the first detection of this organosulfur species in the interstellar medium, during the exploration of an ultradeep molecular line survey performed toward the Galactic Center molecular cloud G+0.693-0.027 with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. We derive a molecular column density of $N$ = (2.6 $\pm$ 0.3)$\times$10$^{13}$ cm$^{-2}$, yielding a fractional abundance relative to H$_2$ of $\sim$1.9$\times$10$^{-10}$. This implies that DMS is a factor of $\sim$1.6 times less abundant than its structural isomer CH$_3$CH$_2$SH and $\sim$30 times less abundant than its O-analogue dimethyl ether (CH$_3$OCH$_3$) toward this cloud, in excellent agreement with previous results on various O/S pairs. Furthermore, we find a remarkable resemblance between the relative abundance of DMS/CH$_3$OH in G+0.693-0.027 ($\sim$1.7$\times$10$^{-3}$) and in the comet ($\sim$1.3$\times$10$^{-3}$). Although the chemistry of DMS beyond Earth is yet to be fully disclosed, this discovery provides conclusive observational evidence on its efficient abiotic production in the interstellar medium, casting doubts about using DMS as a reliable biomarker in exoplanet science. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2501_08892 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | On the abiotic origin of dimethyl sulfide: discovery of DMS in the Interstellar Medium Sanz-Novo, Miguel Rivilla, Víctor M. Endres, Christian P. Lattanzi, Valerio Jiménez-Serra, Izaskun Colzi, Laura Zeng, Shaoshan Megías, Andrés López-Gallifa, Álvaro Martínez-Henares, Antonio Andrés, David San Tercero, Belén de Vicente, Pablo Martín, Sergio Requena-Torres, Miguel A. Caselli, Paola Martín-Pintado, Jesús Astrophysics of Galaxies Following the discovery of dimethyl sulfide (CH$_3$SCH$_3$, DMS) signatures in comet 67P/Churyumov-Gerasimenko, we report the first detection of this organosulfur species in the interstellar medium, during the exploration of an ultradeep molecular line survey performed toward the Galactic Center molecular cloud G+0.693-0.027 with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. We derive a molecular column density of $N$ = (2.6 $\pm$ 0.3)$\times$10$^{13}$ cm$^{-2}$, yielding a fractional abundance relative to H$_2$ of $\sim$1.9$\times$10$^{-10}$. This implies that DMS is a factor of $\sim$1.6 times less abundant than its structural isomer CH$_3$CH$_2$SH and $\sim$30 times less abundant than its O-analogue dimethyl ether (CH$_3$OCH$_3$) toward this cloud, in excellent agreement with previous results on various O/S pairs. Furthermore, we find a remarkable resemblance between the relative abundance of DMS/CH$_3$OH in G+0.693-0.027 ($\sim$1.7$\times$10$^{-3}$) and in the comet ($\sim$1.3$\times$10$^{-3}$). Although the chemistry of DMS beyond Earth is yet to be fully disclosed, this discovery provides conclusive observational evidence on its efficient abiotic production in the interstellar medium, casting doubts about using DMS as a reliable biomarker in exoplanet science. |
| title | On the abiotic origin of dimethyl sulfide: discovery of DMS in the Interstellar Medium |
| topic | Astrophysics of Galaxies |
| url | https://arxiv.org/abs/2501.08892 |