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Main Authors: Cherruault, Valentin, Camerel, Franck, Morin, Julien, Triadon, Amédée, Godin, Nicolas, Mongin, Olivier, Bergamini, Jean-François, Vacher, Antoine, Humphrey, Mark G., Lorenc, Maciej, Paul, Frederic, Pezeril, Thomas
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2501.12912
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author Cherruault, Valentin
Camerel, Franck
Morin, Julien
Triadon, Amédée
Godin, Nicolas
Mongin, Olivier
Bergamini, Jean-François
Vacher, Antoine
Humphrey, Mark G.
Lorenc, Maciej
Paul, Frederic
Pezeril, Thomas
author_facet Cherruault, Valentin
Camerel, Franck
Morin, Julien
Triadon, Amédée
Godin, Nicolas
Mongin, Olivier
Bergamini, Jean-François
Vacher, Antoine
Humphrey, Mark G.
Lorenc, Maciej
Paul, Frederic
Pezeril, Thomas
contents Improving the efficiency of photothermal (PT) therapies and photoacoustic (PA) imaging at the microscopic scale hinges on developing multiphoton-absorbing photothermal molecules or contrast agents that operate in the near-infrared (NIR) range. These advanced agents or molecules will enable excitation with NIR lasers, in an improved transparency range for biological tissues, while enabling minute, highly localized spatial control of the excitation area. However, progress in this field requires innovative experimental techniques to characterize photothermal and photoacoustic effects under multiphoton excitation. In this article, we showcase a study of a model organometallic molecular compound excited via two-photon absorption (2PA) using femtosecond laser pulses. Based on a time-domain Brillouin scattering technique, well adapted for investigating ultrafast nonlinear optical absorption processes in ultrathin films on substrates, we determine the effective nonlinear absorption coefficients of the compound directly linked to PT/PA. Our findings provide a practical approach for exploring and optimizing nonlinear PT/PA absorbers and contrast agents.
format Preprint
id arxiv_https___arxiv_org_abs_2501_12912
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Quantification of Ultrafast Nonlinear Photothermal and Photoacoustic Effects in Molecular Thin Films via Time-Domain Brillouin Scattering
Cherruault, Valentin
Camerel, Franck
Morin, Julien
Triadon, Amédée
Godin, Nicolas
Mongin, Olivier
Bergamini, Jean-François
Vacher, Antoine
Humphrey, Mark G.
Lorenc, Maciej
Paul, Frederic
Pezeril, Thomas
Optics
Improving the efficiency of photothermal (PT) therapies and photoacoustic (PA) imaging at the microscopic scale hinges on developing multiphoton-absorbing photothermal molecules or contrast agents that operate in the near-infrared (NIR) range. These advanced agents or molecules will enable excitation with NIR lasers, in an improved transparency range for biological tissues, while enabling minute, highly localized spatial control of the excitation area. However, progress in this field requires innovative experimental techniques to characterize photothermal and photoacoustic effects under multiphoton excitation. In this article, we showcase a study of a model organometallic molecular compound excited via two-photon absorption (2PA) using femtosecond laser pulses. Based on a time-domain Brillouin scattering technique, well adapted for investigating ultrafast nonlinear optical absorption processes in ultrathin films on substrates, we determine the effective nonlinear absorption coefficients of the compound directly linked to PT/PA. Our findings provide a practical approach for exploring and optimizing nonlinear PT/PA absorbers and contrast agents.
title Quantification of Ultrafast Nonlinear Photothermal and Photoacoustic Effects in Molecular Thin Films via Time-Domain Brillouin Scattering
topic Optics
url https://arxiv.org/abs/2501.12912