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| Main Authors: | , , , , , , , , , |
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| Format: | Preprint |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2501.13245 |
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| _version_ | 1866915117517504512 |
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| author | Chung, Cheng-Chu Li, Ruipeng Veith, Gabriel M. Zhang, Honghu Camino, Fernando Lu, Ming Tiwale, Nikhil Zhang, Sheng Yager, Kevin Chen-Wiegart, Yu-chen Karen |
| author_facet | Chung, Cheng-Chu Li, Ruipeng Veith, Gabriel M. Zhang, Honghu Camino, Fernando Lu, Ming Tiwale, Nikhil Zhang, Sheng Yager, Kevin Chen-Wiegart, Yu-chen Karen |
| contents | Thin-film solid-state metal dealloying (thin-film SSMD) is a promising method for fabricating nanostructures with controlled morphology and efficiency, offering advantages over conventional bulk materials processing methods for integration into practical applications. Although machine learning (ML) has facilitated the design of dealloying systems, the selection of key thermal treatment parameters for nanostructure formation remains largely unknown and dependent on experimental trial and error. To overcome this challenge, a workflow enabling high-throughput characterization of thermal treatment parameters while probing local nanostructures of thin-film samples is needed. In this work, a laser-based thermal treatment is demonstrated to create temperature gradients on single thin-film samples of Nb-Al/Sc and Nb-Al/Cu. This continuous thermal space enables observation of dealloying transitions and the resulting nanostructures of interest. Through synchrotron X-ray multimodal and high-throughput characterization, critical transitions and nanostructures can be rapidly captured and subsequently verified using electron microscopy. The key temperatures driving chemical reactions and morphological evolutions are clearly identified within this framework. While the oxidation process may contribute to nanostructure formation during thin-film treatment, the dealloying process at the dealloying front involves interactions solely between the dealloying elements, highlighting the availability and viability of the selected systems. This approach enables efficient exploration of the dealloying process and validation of ML predictions, thereby accelerating the discovery of thin-film SSMD systems with targeted nanostructures. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2501_13245 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Accelerating Discovery of Solid-State Thin-Film Metal Dealloying for 3D Nanoarchitecture Materials Design through Laser Thermal Gradient Treatment Chung, Cheng-Chu Li, Ruipeng Veith, Gabriel M. Zhang, Honghu Camino, Fernando Lu, Ming Tiwale, Nikhil Zhang, Sheng Yager, Kevin Chen-Wiegart, Yu-chen Karen Materials Science Thin-film solid-state metal dealloying (thin-film SSMD) is a promising method for fabricating nanostructures with controlled morphology and efficiency, offering advantages over conventional bulk materials processing methods for integration into practical applications. Although machine learning (ML) has facilitated the design of dealloying systems, the selection of key thermal treatment parameters for nanostructure formation remains largely unknown and dependent on experimental trial and error. To overcome this challenge, a workflow enabling high-throughput characterization of thermal treatment parameters while probing local nanostructures of thin-film samples is needed. In this work, a laser-based thermal treatment is demonstrated to create temperature gradients on single thin-film samples of Nb-Al/Sc and Nb-Al/Cu. This continuous thermal space enables observation of dealloying transitions and the resulting nanostructures of interest. Through synchrotron X-ray multimodal and high-throughput characterization, critical transitions and nanostructures can be rapidly captured and subsequently verified using electron microscopy. The key temperatures driving chemical reactions and morphological evolutions are clearly identified within this framework. While the oxidation process may contribute to nanostructure formation during thin-film treatment, the dealloying process at the dealloying front involves interactions solely between the dealloying elements, highlighting the availability and viability of the selected systems. This approach enables efficient exploration of the dealloying process and validation of ML predictions, thereby accelerating the discovery of thin-film SSMD systems with targeted nanostructures. |
| title | Accelerating Discovery of Solid-State Thin-Film Metal Dealloying for 3D Nanoarchitecture Materials Design through Laser Thermal Gradient Treatment |
| topic | Materials Science |
| url | https://arxiv.org/abs/2501.13245 |