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Main Authors: Yang, F., Li, X. J., Talbayev, D., Chen, L. Q.
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2501.14655
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author Yang, F.
Li, X. J.
Talbayev, D.
Chen, L. Q.
author_facet Yang, F.
Li, X. J.
Talbayev, D.
Chen, L. Q.
contents Recent terahertz-pump second-harmonic-generation(SHG)-probe measurements of quantum paraelectrics observed a significant long-lived non-oscillatory SHG component following an ultrafast resonant excitation of the soft mode, which was interpreted as a signature of terahertz-induced transient ferroelectric order. Here we propose a temperature-dependent dynamic model incorporating the hot-phonon effect to simulate the soft-mode behaviors under ultrafast terahertz excitation. Its application to paraelectric KTaO3 produces quantitatively most of the features exhibited in our time-resolved SHG measurements and those in existing literature, including a long-lived non-oscillatory SHG response, SHG oscillations at twice the soft-mode frequency, SHG dampings as well as temperature and field-strength dependencies. We conclude that the observed terahertz-induced non-oscillatory SHG response in quantum paraelectrics is a consequence of the induced nonequilibrium hot-phonon effect, offering an alternative to its existing interpretation as a signature of transient ferroelectric order.
format Preprint
id arxiv_https___arxiv_org_abs_2501_14655
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Terahertz-induced second-harmonic generation in quantum paraelectrics: hot-phonon effect
Yang, F.
Li, X. J.
Talbayev, D.
Chen, L. Q.
Materials Science
Optics
Recent terahertz-pump second-harmonic-generation(SHG)-probe measurements of quantum paraelectrics observed a significant long-lived non-oscillatory SHG component following an ultrafast resonant excitation of the soft mode, which was interpreted as a signature of terahertz-induced transient ferroelectric order. Here we propose a temperature-dependent dynamic model incorporating the hot-phonon effect to simulate the soft-mode behaviors under ultrafast terahertz excitation. Its application to paraelectric KTaO3 produces quantitatively most of the features exhibited in our time-resolved SHG measurements and those in existing literature, including a long-lived non-oscillatory SHG response, SHG oscillations at twice the soft-mode frequency, SHG dampings as well as temperature and field-strength dependencies. We conclude that the observed terahertz-induced non-oscillatory SHG response in quantum paraelectrics is a consequence of the induced nonequilibrium hot-phonon effect, offering an alternative to its existing interpretation as a signature of transient ferroelectric order.
title Terahertz-induced second-harmonic generation in quantum paraelectrics: hot-phonon effect
topic Materials Science
Optics
url https://arxiv.org/abs/2501.14655