Quantum oscillations of holes in GaN

Fuente: arXiv
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Autori principali: Chang, Chuan F. C., Dill, Joseph E., Zhang, Zexuan, Chen, Jie-Cheng, Pieczulewski, Naomi, Bader, Samuel J., Valenzuela, Oscar Ayala, Crooker, Scott A., Balakirev, Fedor F., McDonald, Ross D., Encomendero, Jimy, Muller, David A., Giustino, Feliciano, Jena, Debdeep, Xing, Huili Grace
Natura: Preprint
Pubblicazione: 2025
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author Chang, Chuan F. C.
Dill, Joseph E.
Zhang, Zexuan
Chen, Jie-Cheng
Pieczulewski, Naomi
Bader, Samuel J.
Valenzuela, Oscar Ayala
Crooker, Scott A.
Balakirev, Fedor F.
McDonald, Ross D.
Encomendero, Jimy
Muller, David A.
Giustino, Feliciano
Jena, Debdeep
Xing, Huili Grace
author_facet Chang, Chuan F. C.
Dill, Joseph E.
Zhang, Zexuan
Chen, Jie-Cheng
Pieczulewski, Naomi
Bader, Samuel J.
Valenzuela, Oscar Ayala
Crooker, Scott A.
Balakirev, Fedor F.
McDonald, Ross D.
Encomendero, Jimy
Muller, David A.
Giustino, Feliciano
Jena, Debdeep
Xing, Huili Grace
contents GaN has emerged to be a major semiconductor akin to silicon due to its revolutionary impacts in solid state lighting, critically enabled by p-type doping, and high-performance radio-frequency and power electronics. Suffering from inefficient hole doping and low hole mobility, quantum oscillations in p-type GaN have not been observed, hindering fundamental studies of valence bands and hole transport in GaN. Here, we present the first observation of quantum oscillations of holes in GaN. Shubnikov-de Haas (SdH) oscillations in hole resistivity are observed in a quantum-confined two-dimensional hole gas at a GaN/AlN interface, where polarization-induced doping overcomes thermal freeze-out, and a sharp and clean interface boosts the hole mobility enough to unmask the quantum oscillations. These holes degenerately occupy the light and heavy hole bands of GaN and have record-high mobilities of ~1900 cm2/Vs and ~400 cm2/Vs at 3K, respectively. We use magnetic fields up to 72 T to resolve SdH oscillations of holes from both valence bands to extract their respective sheet densities, quantum scattering times, and the effective masses of light holes (0.5-0.7 m0) and heavy holes (1.9 m0). SdH oscillations of heavy and light holes in GaN constitute a direct metrology of valence bands and open new venues for quantum engineering in this technologically important semiconductor. Like strained silicon transistors, strain-engineering of the valence bands of GaN is predicted to dramatically improve hole mobilities by reducing the hole effective mass, a proposal that can now be explored experimentally, particularly in a fully fabricated transistor, using quantum oscillations. Furthermore, the findings of this work suggest a blueprint to create 2D hole gases and observe quantum oscillations of holes in related wide bandgap semiconductors such as SiC and ZnO in which such techniques are not yet possible.
format Preprint
id arxiv_https___arxiv_org_abs_2501_16213
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Quantum oscillations of holes in GaN
Chang, Chuan F. C.
Dill, Joseph E.
Zhang, Zexuan
Chen, Jie-Cheng
Pieczulewski, Naomi
Bader, Samuel J.
Valenzuela, Oscar Ayala
Crooker, Scott A.
Balakirev, Fedor F.
McDonald, Ross D.
Encomendero, Jimy
Muller, David A.
Giustino, Feliciano
Jena, Debdeep
Xing, Huili Grace
Mesoscale and Nanoscale Physics
Materials Science
Applied Physics
GaN has emerged to be a major semiconductor akin to silicon due to its revolutionary impacts in solid state lighting, critically enabled by p-type doping, and high-performance radio-frequency and power electronics. Suffering from inefficient hole doping and low hole mobility, quantum oscillations in p-type GaN have not been observed, hindering fundamental studies of valence bands and hole transport in GaN. Here, we present the first observation of quantum oscillations of holes in GaN. Shubnikov-de Haas (SdH) oscillations in hole resistivity are observed in a quantum-confined two-dimensional hole gas at a GaN/AlN interface, where polarization-induced doping overcomes thermal freeze-out, and a sharp and clean interface boosts the hole mobility enough to unmask the quantum oscillations. These holes degenerately occupy the light and heavy hole bands of GaN and have record-high mobilities of ~1900 cm2/Vs and ~400 cm2/Vs at 3K, respectively. We use magnetic fields up to 72 T to resolve SdH oscillations of holes from both valence bands to extract their respective sheet densities, quantum scattering times, and the effective masses of light holes (0.5-0.7 m0) and heavy holes (1.9 m0). SdH oscillations of heavy and light holes in GaN constitute a direct metrology of valence bands and open new venues for quantum engineering in this technologically important semiconductor. Like strained silicon transistors, strain-engineering of the valence bands of GaN is predicted to dramatically improve hole mobilities by reducing the hole effective mass, a proposal that can now be explored experimentally, particularly in a fully fabricated transistor, using quantum oscillations. Furthermore, the findings of this work suggest a blueprint to create 2D hole gases and observe quantum oscillations of holes in related wide bandgap semiconductors such as SiC and ZnO in which such techniques are not yet possible.
title Quantum oscillations of holes in GaN
topic Mesoscale and Nanoscale Physics
Materials Science
Applied Physics
url https://arxiv.org/abs/2501.16213