Mutual control of critical temperature, residual resistance ratio, stress, and roughness for sputtered Nb films

Fuente: arXiv
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Auteurs principaux: Zikiy, E. V., Stepanov, I. A., Bukatin, S. V., Baklykov, D. A., Teleganov, M. I., Krivko, E. A., Smirnov, N. S., Ryzhikov, I. A., Bychkov, S. P., Kotenkov, S. A., Korshakov, N. D., Agafonova, J. A., Rodionov, I. A.
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Publié: 2025
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author Zikiy, E. V.
Stepanov, I. A.
Bukatin, S. V.
Baklykov, D. A.
Teleganov, M. I.
Krivko, E. A.
Smirnov, N. S.
Ryzhikov, I. A.
Bychkov, S. P.
Kotenkov, S. A.
Korshakov, N. D.
Agafonova, J. A.
Rodionov, I. A.
author_facet Zikiy, E. V.
Stepanov, I. A.
Bukatin, S. V.
Baklykov, D. A.
Teleganov, M. I.
Krivko, E. A.
Smirnov, N. S.
Ryzhikov, I. A.
Bychkov, S. P.
Kotenkov, S. A.
Korshakov, N. D.
Agafonova, J. A.
Rodionov, I. A.
contents Superconducting single quantum logic integrated circuits traditionally exploit magnetron sputtered niobium thin films on silicon oxide substrates. The sputtering depends on multiple process parameters, which dramatically affect mechanical, electrical, and cryogenic properties of Nb thin films. In this work, we focus on the comprehensive relationship study between 200-nm Nb film characteristics and their intrinsic stress. It is shown that there is a critical value of the working pressure pcritical at the fixed sputtering power above which stress in the film relaxes whereas the film properties degrade significantly. Below pcritical one can control intrinsic stress in the wide range from -400 MPa to +600 MPa maintaining perfect film surface with a 0.8 nm roughness (Rq), electrical resistivity less than 20 uOhm*cm, critical superconducting transition temperature above 8.9 K and residual resistance ratio over 6.4. We suggest a modified kinetic model to predict Nb films stress with the linear dependence of high-energy parameters on the working pressure replaced with an exponential one, which allowed reduction of the approximation error from 20 to 8%.
format Preprint
id arxiv_https___arxiv_org_abs_2502_03299
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Mutual control of critical temperature, residual resistance ratio, stress, and roughness for sputtered Nb films
Zikiy, E. V.
Stepanov, I. A.
Bukatin, S. V.
Baklykov, D. A.
Teleganov, M. I.
Krivko, E. A.
Smirnov, N. S.
Ryzhikov, I. A.
Bychkov, S. P.
Kotenkov, S. A.
Korshakov, N. D.
Agafonova, J. A.
Rodionov, I. A.
Materials Science
Superconductivity
Applied Physics
Superconducting single quantum logic integrated circuits traditionally exploit magnetron sputtered niobium thin films on silicon oxide substrates. The sputtering depends on multiple process parameters, which dramatically affect mechanical, electrical, and cryogenic properties of Nb thin films. In this work, we focus on the comprehensive relationship study between 200-nm Nb film characteristics and their intrinsic stress. It is shown that there is a critical value of the working pressure pcritical at the fixed sputtering power above which stress in the film relaxes whereas the film properties degrade significantly. Below pcritical one can control intrinsic stress in the wide range from -400 MPa to +600 MPa maintaining perfect film surface with a 0.8 nm roughness (Rq), electrical resistivity less than 20 uOhm*cm, critical superconducting transition temperature above 8.9 K and residual resistance ratio over 6.4. We suggest a modified kinetic model to predict Nb films stress with the linear dependence of high-energy parameters on the working pressure replaced with an exponential one, which allowed reduction of the approximation error from 20 to 8%.
title Mutual control of critical temperature, residual resistance ratio, stress, and roughness for sputtered Nb films
topic Materials Science
Superconductivity
Applied Physics
url https://arxiv.org/abs/2502.03299