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Main Authors: Liu, Lei, Guo, Guanlong, Wang, Kaiyu, Chen, Linke, Fan, Yangyang, Torres, Sergio Andres Galindo, Lv, Jiu-an, Huppert, Herbert E., Wei, Changfu, Lei, Liang
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2502.03476
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author Liu, Lei
Guo, Guanlong
Wang, Kaiyu
Chen, Linke
Fan, Yangyang
Torres, Sergio Andres Galindo
Lv, Jiu-an
Huppert, Herbert E.
Wei, Changfu
Lei, Liang
author_facet Liu, Lei
Guo, Guanlong
Wang, Kaiyu
Chen, Linke
Fan, Yangyang
Torres, Sergio Andres Galindo
Lv, Jiu-an
Huppert, Herbert E.
Wei, Changfu
Lei, Liang
contents It is common belief that the equilibrium contact angle, corresponding to the minimum system energy state, lies between advancing and receding contact angles. Here, we derive advancing and receding contact angles considering the micro contacting processes on ideal rough 2D surfaces. Equilibrium contact angles obtained via energy minimization can be smaller than the receding contact angle and reach 0 degrees, at which hysteresis diminishes on the super-hydrophilic surface. Gibbs free energy analyses, numerical simulations and physical experiments all confirm these new findings.
format Preprint
id arxiv_https___arxiv_org_abs_2502_03476
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Achieve equilibrium outside the contact angle hysteresis
Liu, Lei
Guo, Guanlong
Wang, Kaiyu
Chen, Linke
Fan, Yangyang
Torres, Sergio Andres Galindo
Lv, Jiu-an
Huppert, Herbert E.
Wei, Changfu
Lei, Liang
Soft Condensed Matter
It is common belief that the equilibrium contact angle, corresponding to the minimum system energy state, lies between advancing and receding contact angles. Here, we derive advancing and receding contact angles considering the micro contacting processes on ideal rough 2D surfaces. Equilibrium contact angles obtained via energy minimization can be smaller than the receding contact angle and reach 0 degrees, at which hysteresis diminishes on the super-hydrophilic surface. Gibbs free energy analyses, numerical simulations and physical experiments all confirm these new findings.
title Achieve equilibrium outside the contact angle hysteresis
topic Soft Condensed Matter
url https://arxiv.org/abs/2502.03476