High pressure structural and lattice dynamics study of α-In$_2$Se$_3$
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2025
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| _version_ | 1866929706240049152 |
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| author | Feng, Shiyu Sun, Baihong Lu, Wenting Zou, Haikai Wei, Chenxin Zhang, Qian Wang, Bihan Kunz, Martin Kadobayashi, Hirokazu Ahmad, Azkar Saeed Koren, Elad Stavrou, Elissaios |
| author_facet | Feng, Shiyu Sun, Baihong Lu, Wenting Zou, Haikai Wei, Chenxin Zhang, Qian Wang, Bihan Kunz, Martin Kadobayashi, Hirokazu Ahmad, Azkar Saeed Koren, Elad Stavrou, Elissaios |
| contents | Layered $α$-In$_2$Se$_3$has been studied using a concomitant in-situ synchrotron angle dispersive powder x-ray diffraction and Raman spectroscopy study in a diamond anvil cell up to 60+ GPa, at room temperature. Helium, that remains fairly hydrostatic up to the highest pressure in this study, was used as the pressure-transmitting medium. The results from both experimental methods reveal a pressure-induced structural phase transition from $α$-In$_2$Se$_3$ to a monoclinic $β$'-In2Se3 structure at $\approx$1 GPa, in agreement with previous studies. Based on our detailed measurements using both experimental techniques and F-f formalism, the $β$'-In$_2$Se$_3$ structure remains stable up to 45 GPa, without a clear indication of a phase transition towards the previously reported $β$-In2Se3 phase. Above this pressure, In$_2$Se$_3$ adopts a disordered solid-solution-like orthorhombic structure, phase IV. The results are discussed in comparison with the relevant previous studies of $α$-In$_2$Se$_3$ under pressure. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2502_05927 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | High pressure structural and lattice dynamics study of α-In$_2$Se$_3$ Feng, Shiyu Sun, Baihong Lu, Wenting Zou, Haikai Wei, Chenxin Zhang, Qian Wang, Bihan Kunz, Martin Kadobayashi, Hirokazu Ahmad, Azkar Saeed Koren, Elad Stavrou, Elissaios Materials Science Layered $α$-In$_2$Se$_3$has been studied using a concomitant in-situ synchrotron angle dispersive powder x-ray diffraction and Raman spectroscopy study in a diamond anvil cell up to 60+ GPa, at room temperature. Helium, that remains fairly hydrostatic up to the highest pressure in this study, was used as the pressure-transmitting medium. The results from both experimental methods reveal a pressure-induced structural phase transition from $α$-In$_2$Se$_3$ to a monoclinic $β$'-In2Se3 structure at $\approx$1 GPa, in agreement with previous studies. Based on our detailed measurements using both experimental techniques and F-f formalism, the $β$'-In$_2$Se$_3$ structure remains stable up to 45 GPa, without a clear indication of a phase transition towards the previously reported $β$-In2Se3 phase. Above this pressure, In$_2$Se$_3$ adopts a disordered solid-solution-like orthorhombic structure, phase IV. The results are discussed in comparison with the relevant previous studies of $α$-In$_2$Se$_3$ under pressure. |
| title | High pressure structural and lattice dynamics study of α-In$_2$Se$_3$ |
| topic | Materials Science |
| url | https://arxiv.org/abs/2502.05927 |