HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary

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Main Authors: Matthews, Elisabeth C., Mollière, Paul, Kühnle, Helena, Patapis, Polychronis, Whiteford, Niall, Samland, Matthias, Lagage, Pierre-Olivier, Waters, Rens, Tsai, Shang-Min, Zahnle, Kevin, Guedel, Manuel, Henning, Thomas, Vandenbussche, Bart, Absil, Olivier, Argyriou, Ioannis, Barrado, David, Coulais, Alain, Glauser, Adrian M., Olofsson, Goran, Pye, John P., Rouan, Daniel, Royer, Pierre, van Dishoeck, Ewine F., Ray, T. P., Östlin, Göran
Format: Preprint
Published: 2025
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author Matthews, Elisabeth C.
Mollière, Paul
Kühnle, Helena
Patapis, Polychronis
Whiteford, Niall
Samland, Matthias
Lagage, Pierre-Olivier
Waters, Rens
Tsai, Shang-Min
Zahnle, Kevin
Guedel, Manuel
Henning, Thomas
Vandenbussche, Bart
Absil, Olivier
Argyriou, Ioannis
Barrado, David
Coulais, Alain
Glauser, Adrian M.
Olofsson, Goran
Pye, John P.
Rouan, Daniel
Royer, Pierre
van Dishoeck, Ewine F.
Ray, T. P.
Östlin, Göran
author_facet Matthews, Elisabeth C.
Mollière, Paul
Kühnle, Helena
Patapis, Polychronis
Whiteford, Niall
Samland, Matthias
Lagage, Pierre-Olivier
Waters, Rens
Tsai, Shang-Min
Zahnle, Kevin
Guedel, Manuel
Henning, Thomas
Vandenbussche, Bart
Absil, Olivier
Argyriou, Ioannis
Barrado, David
Coulais, Alain
Glauser, Adrian M.
Olofsson, Goran
Pye, John P.
Rouan, Daniel
Royer, Pierre
van Dishoeck, Ewine F.
Ray, T. P.
Östlin, Göran
contents T-type brown dwarfs present an opportunity to explore atmospheres teeming with molecules such as H2O, CH4 and NH3, which exhibit a wealth of absorption features in the mid-infrared. With JWST, we can finally explore this chemistry in detail, including for the coldest brown dwarfs that were not yet discovered in the Spitzer era. This allows precise derivations of the molecular abundances, which in turn informs our understanding of vertical transport in these atmospheres and can provide clues about the formation of cold brown dwarfs and exoplanets. This study presents the first JWST/MRS mid-IR spectrum (R ~ 1500-3000) of a T-dwarf: the T8.5+T9 brown dwarf binary WISE J045853.90+643451.9. We fit the spectrum using a parameterized P-T profile and free molecular abundances (i.e., a retrieval analysis), treating the binary as unresolved. We find a good fit with a cloud-free atmosphere and identify H2O, CH4 and NH3 features. Moreover, we make the first detections of HCN and C2H2 (at 13.4$σ$ and 9.5$σ$ respectively) in any brown dwarf atmosphere. The detection of HCN suggests intense vertical mixing ($K_{zz}\sim10^{11}$cm$^2$s$^{-1}$), challenging previous literature derivations of $K_{zz}$ values for T-type brown dwarfs. Even more surprising is the C2H2 detection, which cannot be explained with existing atmospheric models for isolated objects. This result challenges model assumptions about vertical mixing, and/or our understanding of the C2H2 chemical network, or might hint towards a more complex atmospheric processes such as magnetic fields driving aurorae, or lightning driving ionization. These findings open a new frontier in studying carbon chemistry within brown dwarf atmospheres.
format Preprint
id arxiv_https___arxiv_org_abs_2502_13610
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary
Matthews, Elisabeth C.
Mollière, Paul
Kühnle, Helena
Patapis, Polychronis
Whiteford, Niall
Samland, Matthias
Lagage, Pierre-Olivier
Waters, Rens
Tsai, Shang-Min
Zahnle, Kevin
Guedel, Manuel
Henning, Thomas
Vandenbussche, Bart
Absil, Olivier
Argyriou, Ioannis
Barrado, David
Coulais, Alain
Glauser, Adrian M.
Olofsson, Goran
Pye, John P.
Rouan, Daniel
Royer, Pierre
van Dishoeck, Ewine F.
Ray, T. P.
Östlin, Göran
Earth and Planetary Astrophysics
Solar and Stellar Astrophysics
T-type brown dwarfs present an opportunity to explore atmospheres teeming with molecules such as H2O, CH4 and NH3, which exhibit a wealth of absorption features in the mid-infrared. With JWST, we can finally explore this chemistry in detail, including for the coldest brown dwarfs that were not yet discovered in the Spitzer era. This allows precise derivations of the molecular abundances, which in turn informs our understanding of vertical transport in these atmospheres and can provide clues about the formation of cold brown dwarfs and exoplanets. This study presents the first JWST/MRS mid-IR spectrum (R ~ 1500-3000) of a T-dwarf: the T8.5+T9 brown dwarf binary WISE J045853.90+643451.9. We fit the spectrum using a parameterized P-T profile and free molecular abundances (i.e., a retrieval analysis), treating the binary as unresolved. We find a good fit with a cloud-free atmosphere and identify H2O, CH4 and NH3 features. Moreover, we make the first detections of HCN and C2H2 (at 13.4$σ$ and 9.5$σ$ respectively) in any brown dwarf atmosphere. The detection of HCN suggests intense vertical mixing ($K_{zz}\sim10^{11}$cm$^2$s$^{-1}$), challenging previous literature derivations of $K_{zz}$ values for T-type brown dwarfs. Even more surprising is the C2H2 detection, which cannot be explained with existing atmospheric models for isolated objects. This result challenges model assumptions about vertical mixing, and/or our understanding of the C2H2 chemical network, or might hint towards a more complex atmospheric processes such as magnetic fields driving aurorae, or lightning driving ionization. These findings open a new frontier in studying carbon chemistry within brown dwarf atmospheres.
title HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary
topic Earth and Planetary Astrophysics
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2502.13610