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Main Authors: Leung, Michaela, Tsai, Shang-Min, Schwieterman, Edward W, Angerhausen, Daniel, Hansen, Janina
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2502.13856
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author Leung, Michaela
Tsai, Shang-Min
Schwieterman, Edward W
Angerhausen, Daniel
Hansen, Janina
author_facet Leung, Michaela
Tsai, Shang-Min
Schwieterman, Edward W
Angerhausen, Daniel
Hansen, Janina
contents Some sub-Neptune planets may host habitable conditions; for example "Hycean" worlds with H2 envelopes over liquid water oceans can maintain potentially hospitable pressures and temperatures at their surface. Recent JWST observations of K2-18b and TOI-270d have shown that such worlds could be compelling targets for biosignature searches, given their extended scale heights and therefore large atmospheric signatures. Methylated biosignatures, a broad group of gases that can be generated by biological attachment of a CH3 group to an environmental substrate, have been proposed as candidate signs of life for Earth-like exoplanets. However, methyl halides (CH3 + halogen) have not yet been robustly examined with self-consistent photochemical and spectral models for planets with H2-dominated atmospheres. Here we demonstrate that methyl chloride (CH3Cl), predominantly produced by marine microbes, could be detected using JWST in tens of transits or fewer for Hycean planets, comparable to detection requirements for other potential atmospheric biosignatures. The threshold atmospheric mixing ratio for detectability is $\sim$10 ppm, which can accumulate with global fluxes comparable to moderately productive local environments on Earth.
format Preprint
id arxiv_https___arxiv_org_abs_2502_13856
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Examining the Potential for Methyl Halide Accumulation and Detectability in Possible Hycean-Type Atmospheres
Leung, Michaela
Tsai, Shang-Min
Schwieterman, Edward W
Angerhausen, Daniel
Hansen, Janina
Earth and Planetary Astrophysics
Some sub-Neptune planets may host habitable conditions; for example "Hycean" worlds with H2 envelopes over liquid water oceans can maintain potentially hospitable pressures and temperatures at their surface. Recent JWST observations of K2-18b and TOI-270d have shown that such worlds could be compelling targets for biosignature searches, given their extended scale heights and therefore large atmospheric signatures. Methylated biosignatures, a broad group of gases that can be generated by biological attachment of a CH3 group to an environmental substrate, have been proposed as candidate signs of life for Earth-like exoplanets. However, methyl halides (CH3 + halogen) have not yet been robustly examined with self-consistent photochemical and spectral models for planets with H2-dominated atmospheres. Here we demonstrate that methyl chloride (CH3Cl), predominantly produced by marine microbes, could be detected using JWST in tens of transits or fewer for Hycean planets, comparable to detection requirements for other potential atmospheric biosignatures. The threshold atmospheric mixing ratio for detectability is $\sim$10 ppm, which can accumulate with global fluxes comparable to moderately productive local environments on Earth.
title Examining the Potential for Methyl Halide Accumulation and Detectability in Possible Hycean-Type Atmospheres
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2502.13856