The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure
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arXiv
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2025
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| author | Gao, Kun Cerqueira, Tiago F. T. Sanna, Antonio Fang, Yue-Wen Dangić, Đorđe Errea, Ion Wang, Hai-Chen Botti, Silvana Marques, Miguel A. L. |
| author_facet | Gao, Kun Cerqueira, Tiago F. T. Sanna, Antonio Fang, Yue-Wen Dangić, Đorđe Errea, Ion Wang, Hai-Chen Botti, Silvana Marques, Miguel A. L. |
| contents | The theoretical maximum critical temperature ($T_c$) for conventional superconductors at ambient pressure remains a fundamental question in condensed matter physics. Through analysis of electron-phonon calculations for over 20,000 metals, we critically examine this question. We find that while hydride metals can exhibit maximum phonon frequencies of more than 5000 K, the crucial logarithmic average frequency $ω_\text{log}$ rarely exceeds 1800 K. Our data reveals an inherent trade-off between $ω_\text{log}$ and the electron-phonon coupling constant $λ$, suggesting that the optimal Eliashberg function that maximizes $T_c$ is unphysical. Based on our calculations, we identify Li$_2$AgH$_6$ and its sibling Li$_2$AuH$_6$ as theoretical materials that likely approach the practical limit for conventional superconductivity at ambient pressure. Analysis of thermodynamic stability indicates that compounds with higher predicted $T_c$ values are increasingly unstable, making their synthesis challenging. While fundamental physical laws do not strictly limit $T_c$ to low-temperatures, our analysis suggests that achieving room-temperature conventional superconductivity at ambient pressure is extremely unlikely. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2502_18281 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure Gao, Kun Cerqueira, Tiago F. T. Sanna, Antonio Fang, Yue-Wen Dangić, Đorđe Errea, Ion Wang, Hai-Chen Botti, Silvana Marques, Miguel A. L. Superconductivity The theoretical maximum critical temperature ($T_c$) for conventional superconductors at ambient pressure remains a fundamental question in condensed matter physics. Through analysis of electron-phonon calculations for over 20,000 metals, we critically examine this question. We find that while hydride metals can exhibit maximum phonon frequencies of more than 5000 K, the crucial logarithmic average frequency $ω_\text{log}$ rarely exceeds 1800 K. Our data reveals an inherent trade-off between $ω_\text{log}$ and the electron-phonon coupling constant $λ$, suggesting that the optimal Eliashberg function that maximizes $T_c$ is unphysical. Based on our calculations, we identify Li$_2$AgH$_6$ and its sibling Li$_2$AuH$_6$ as theoretical materials that likely approach the practical limit for conventional superconductivity at ambient pressure. Analysis of thermodynamic stability indicates that compounds with higher predicted $T_c$ values are increasingly unstable, making their synthesis challenging. While fundamental physical laws do not strictly limit $T_c$ to low-temperatures, our analysis suggests that achieving room-temperature conventional superconductivity at ambient pressure is extremely unlikely. |
| title | The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure |
| topic | Superconductivity |
| url | https://arxiv.org/abs/2502.18281 |