Confined colloidal droplets dry to form circular mazes

Fuente: arXiv
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Autores principales: Beechey-Newman, Ilaria, Kizilova, Natalya, Hennig, Andreas Andersen, Flekkøy, Eirik Grude, Eiser, Erika
Formato: Preprint
Publicado: 2025
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author Beechey-Newman, Ilaria
Kizilova, Natalya
Hennig, Andreas Andersen
Flekkøy, Eirik Grude
Eiser, Erika
author_facet Beechey-Newman, Ilaria
Kizilova, Natalya
Hennig, Andreas Andersen
Flekkøy, Eirik Grude
Eiser, Erika
contents During drying, particle-laden sessile droplets will leave so-called coffee-stain rings behind. This phenomenon is well-known and well-understood (Deegan et al., Nature 389, 827-829 (1997)). Here we show that when particle-laden droplets confined in a slit are allowed to evaporate very slowly, they do not deposit coffee rings, but form a surprisingly intricate, circular maze-like pattern. We present experiments that illustrate this pattern formation and discuss the factors that determine when such patterns can form. We are not aware of reports of natural examples of the formation of such beautiful patterns under confinement, although it seems likely that they exist.
format Preprint
id arxiv_https___arxiv_org_abs_2502_19604
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Confined colloidal droplets dry to form circular mazes
Beechey-Newman, Ilaria
Kizilova, Natalya
Hennig, Andreas Andersen
Flekkøy, Eirik Grude
Eiser, Erika
Soft Condensed Matter
During drying, particle-laden sessile droplets will leave so-called coffee-stain rings behind. This phenomenon is well-known and well-understood (Deegan et al., Nature 389, 827-829 (1997)). Here we show that when particle-laden droplets confined in a slit are allowed to evaporate very slowly, they do not deposit coffee rings, but form a surprisingly intricate, circular maze-like pattern. We present experiments that illustrate this pattern formation and discuss the factors that determine when such patterns can form. We are not aware of reports of natural examples of the formation of such beautiful patterns under confinement, although it seems likely that they exist.
title Confined colloidal droplets dry to form circular mazes
topic Soft Condensed Matter
url https://arxiv.org/abs/2502.19604