Cyanothiazole Copper(I) Complexes: Uncharted Materials with Exceptional Optical and Conductive Properties
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arXiv
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| Main Authors: | , , , , , , , , , , |
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| Format: | Preprint |
| Published: |
2025
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| _version_ | 1866912251834793984 |
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| author | Gutmańska, Karolina Podborska, Agnieszka Mazur, Tomasz Sławek, Andrzej Sivasamy, Ramesh Maximenko, Alexey Orzeł, Łukasz Oszajca, Janusz Stochel, Grażyna Szaciłowski, Konrad Dołęga, Anna |
| author_facet | Gutmańska, Karolina Podborska, Agnieszka Mazur, Tomasz Sławek, Andrzej Sivasamy, Ramesh Maximenko, Alexey Orzeł, Łukasz Oszajca, Janusz Stochel, Grażyna Szaciłowski, Konrad Dołęga, Anna |
| contents | Cyanothiazoles, small and quite overlooked molecules, possess remarkable optical properties that can be fine-tuned through coordination with transition metals. In this study, we investigate a promising application of cyanothiazoles, where their combination with copper(I) iodide forms a new class of complexes exhibiting outstanding optical properties. X-ray crystallography of copper(I) iodide complexes with isomeric cyanothiazoles revealed key structural features, such as π-π stacking, hydrogen bonding, and rare halogen-chalcogen I-S interactions, enhancing stability and reactivity. Advanced spectroscopy and computational modeling allowed precise identification of spectral signatures in FTIR, NMR, and UV-Vis spectra. Fluorescence studies, along with XANES synchrotron analyses, highlighted their unique thermal and electronic properties, providing a solid foundation for further research in the field. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2502_20848 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Cyanothiazole Copper(I) Complexes: Uncharted Materials with Exceptional Optical and Conductive Properties Gutmańska, Karolina Podborska, Agnieszka Mazur, Tomasz Sławek, Andrzej Sivasamy, Ramesh Maximenko, Alexey Orzeł, Łukasz Oszajca, Janusz Stochel, Grażyna Szaciłowski, Konrad Dołęga, Anna Materials Science Chemical Physics Cyanothiazoles, small and quite overlooked molecules, possess remarkable optical properties that can be fine-tuned through coordination with transition metals. In this study, we investigate a promising application of cyanothiazoles, where their combination with copper(I) iodide forms a new class of complexes exhibiting outstanding optical properties. X-ray crystallography of copper(I) iodide complexes with isomeric cyanothiazoles revealed key structural features, such as π-π stacking, hydrogen bonding, and rare halogen-chalcogen I-S interactions, enhancing stability and reactivity. Advanced spectroscopy and computational modeling allowed precise identification of spectral signatures in FTIR, NMR, and UV-Vis spectra. Fluorescence studies, along with XANES synchrotron analyses, highlighted their unique thermal and electronic properties, providing a solid foundation for further research in the field. |
| title | Cyanothiazole Copper(I) Complexes: Uncharted Materials with Exceptional Optical and Conductive Properties |
| topic | Materials Science Chemical Physics |
| url | https://arxiv.org/abs/2502.20848 |