Determination of Quantum Defects and Core Polarizability of Atomic Cesium via Terahertz and Radio-Frequency Spectroscopy in Thermal Vapor

Fuente: arXiv
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Autori principali: Allinson, Gianluca, Downes, Lucy A., Weatherill, Kevin J., Adams, C. Stuart
Natura: Preprint
Pubblicazione: 2025
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author Allinson, Gianluca
Downes, Lucy A.
Weatherill, Kevin J.
Adams, C. Stuart
author_facet Allinson, Gianluca
Downes, Lucy A.
Weatherill, Kevin J.
Adams, C. Stuart
contents We present new measurements of quantum defects and core polarizabilities in cesium ($^{133}$Cs), based on transition frequency measurements between Rydberg states ($14 \leq n \leq 38$) obtained through terahertz (THz) and radio-frequency spectroscopy in a thermal atomic vapor. %By detuning resonant fields coupling neighbouring Rydberg states, we observe a detuning-dependent asymmetry in the line shape which can be used to extract the frequency of the transition. We perform a global fitting of our measurements to extract quantum defects of the $s_{1/2}$, $p_{1/2}$, $p_{3/2}$, $d_{3/2}$, $d_{5/2}$, $f_{5/2}$, $f_{7/2}$, $g_{7/2}$ and $g_{9/2}$ electronic states. Transitions between high angular momentum states ($4 \leq \ell \leq 8$) were measured to extract the Cs$^{+}$ dipole and quadrupole polarizabilities. We find $α_{d} = 15.729(18)$ $a_{0}^{3}$ and $α_{q} = 76.3(1.9)$ $a_{0}^{5}$ respectively. Using these results, and accounting for the covariances between parameters in the global fit, the energies for $n\ell_{j}$ Rydberg states can be estimated to a precision of a few MHz or less.
format Preprint
id arxiv_https___arxiv_org_abs_2502_20961
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Determination of Quantum Defects and Core Polarizability of Atomic Cesium via Terahertz and Radio-Frequency Spectroscopy in Thermal Vapor
Allinson, Gianluca
Downes, Lucy A.
Weatherill, Kevin J.
Adams, C. Stuart
Atomic Physics
We present new measurements of quantum defects and core polarizabilities in cesium ($^{133}$Cs), based on transition frequency measurements between Rydberg states ($14 \leq n \leq 38$) obtained through terahertz (THz) and radio-frequency spectroscopy in a thermal atomic vapor. %By detuning resonant fields coupling neighbouring Rydberg states, we observe a detuning-dependent asymmetry in the line shape which can be used to extract the frequency of the transition. We perform a global fitting of our measurements to extract quantum defects of the $s_{1/2}$, $p_{1/2}$, $p_{3/2}$, $d_{3/2}$, $d_{5/2}$, $f_{5/2}$, $f_{7/2}$, $g_{7/2}$ and $g_{9/2}$ electronic states. Transitions between high angular momentum states ($4 \leq \ell \leq 8$) were measured to extract the Cs$^{+}$ dipole and quadrupole polarizabilities. We find $α_{d} = 15.729(18)$ $a_{0}^{3}$ and $α_{q} = 76.3(1.9)$ $a_{0}^{5}$ respectively. Using these results, and accounting for the covariances between parameters in the global fit, the energies for $n\ell_{j}$ Rydberg states can be estimated to a precision of a few MHz or less.
title Determination of Quantum Defects and Core Polarizability of Atomic Cesium via Terahertz and Radio-Frequency Spectroscopy in Thermal Vapor
topic Atomic Physics
url https://arxiv.org/abs/2502.20961