Partial ionization cross sections of isobutanol

Fuente: arXiv
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Autores principales: Shanmugasundaram, Suriyaprasanth, Gupta, Dhanoj
Formato: Preprint
Publicado: 2025
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author Shanmugasundaram, Suriyaprasanth
Gupta, Dhanoj
author_facet Shanmugasundaram, Suriyaprasanth
Gupta, Dhanoj
contents The electron and positron impact partial ionization cross sections (PICS) for isobutanol were calculated using variants of the binary encounter Bethe model (BEB). The modified BEB (mBEB) model and the mass spectrum dependent (MSD) method are used to calculate the PICS of cationic fragments of isobutanol. Also for calculating the positron impact ionization and dissociative ionization cross sections, we have used the BEB-0 model and the BEB-W model which are scaled Wannier threshold laws along with the BEB-A and BEB-B models which obey Jansen's threshold law. The study also compares the PICS calculated from other isomers of butanol presented in the literature. We also presented the synthetic electron impact mass spectrum of isobutanol which is compared with the experimental measurements.
format Preprint
id arxiv_https___arxiv_org_abs_2503_00360
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Partial ionization cross sections of isobutanol
Shanmugasundaram, Suriyaprasanth
Gupta, Dhanoj
Chemical Physics
The electron and positron impact partial ionization cross sections (PICS) for isobutanol were calculated using variants of the binary encounter Bethe model (BEB). The modified BEB (mBEB) model and the mass spectrum dependent (MSD) method are used to calculate the PICS of cationic fragments of isobutanol. Also for calculating the positron impact ionization and dissociative ionization cross sections, we have used the BEB-0 model and the BEB-W model which are scaled Wannier threshold laws along with the BEB-A and BEB-B models which obey Jansen's threshold law. The study also compares the PICS calculated from other isomers of butanol presented in the literature. We also presented the synthetic electron impact mass spectrum of isobutanol which is compared with the experimental measurements.
title Partial ionization cross sections of isobutanol
topic Chemical Physics
url https://arxiv.org/abs/2503.00360