A neural-network-based Python package for performing large-scale atomic CI using pCI and other high-performance atomic codes

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Main Authors: Bilous, Pavlo, Cheung, Charles, Safronova, Marianna
Format: Preprint
Published: 2025
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author Bilous, Pavlo
Cheung, Charles
Safronova, Marianna
author_facet Bilous, Pavlo
Cheung, Charles
Safronova, Marianna
contents Modern atomic physics applications in science and technology pose ever higher demands on the precision of computations of properties of atoms and ions. Especially challenging is the modeling of electronic correlations within the configuration interaction (CI) framework, which often requires expansions of the atomic state in huge bases of Slater determinants or configuration state functions. This can easily render the problem intractable even for highly efficient atomic codes running on distributed supercomputer systems. Recently, we have successfully addressed this problem using a neural-network (NN) approach [1]. In this work, we present our Python code for performing NN-supported large-scale atomic CI using pCI [2] and other high-performance atomic codes. [1] P. Bilous, C. Cheung, and M. Safronova, Phys. Rev. A 110 042818 (2024). [2] C. Cheung, M. G. Kozlov, S. G. Porsev, M. S. Safronova, I. I. Tupitsyn, A. I. Bondarev, Comput. Phys. Commun. 308 109463 (2025).
format Preprint
id arxiv_https___arxiv_org_abs_2503_01379
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle A neural-network-based Python package for performing large-scale atomic CI using pCI and other high-performance atomic codes
Bilous, Pavlo
Cheung, Charles
Safronova, Marianna
Atomic Physics
Modern atomic physics applications in science and technology pose ever higher demands on the precision of computations of properties of atoms and ions. Especially challenging is the modeling of electronic correlations within the configuration interaction (CI) framework, which often requires expansions of the atomic state in huge bases of Slater determinants or configuration state functions. This can easily render the problem intractable even for highly efficient atomic codes running on distributed supercomputer systems. Recently, we have successfully addressed this problem using a neural-network (NN) approach [1]. In this work, we present our Python code for performing NN-supported large-scale atomic CI using pCI [2] and other high-performance atomic codes. [1] P. Bilous, C. Cheung, and M. Safronova, Phys. Rev. A 110 042818 (2024). [2] C. Cheung, M. G. Kozlov, S. G. Porsev, M. S. Safronova, I. I. Tupitsyn, A. I. Bondarev, Comput. Phys. Commun. 308 109463 (2025).
title A neural-network-based Python package for performing large-scale atomic CI using pCI and other high-performance atomic codes
topic Atomic Physics
url https://arxiv.org/abs/2503.01379