Micro/nanoscale spacers for enhanced thermophotovoltaic and thermionic energy conversion: a comprehensive review

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Main Authors: Loubet, Nicolas A, Bezdjian, Katie, Lopez, Esther, Datas, Alejandro
Format: Preprint
Published: 2025
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author Loubet, Nicolas A
Bezdjian, Katie
Lopez, Esther
Datas, Alejandro
author_facet Loubet, Nicolas A
Bezdjian, Katie
Lopez, Esther
Datas, Alejandro
contents Thermionics and thermophotovoltaics are solid-state technologies that convert high-temperature heat into electricity by utilizing fundamental particles, electrons in thermionics and photons in thermophotovoltaics, as energy carriers. Both systems have the potential to achieve high efficiency and power density, contingent on the optimization of radiative/electronic energy fluxes. A critical factor in enhancing energy flux in these devices is the introduction of microscale (thermionics) or nanoscale (thermophotovoltaics) gaps between the hot thermal emitter and the cooler receiver. In thermionic converters, microscale gaps mitigate space charge effects that create energy barriers to electron flow. For thermophotovoltaic systems, nanoscale gaps facilitate photon tunneling, significantly boosting photon flux towards the thermophotovoltaic cell. Forming these small-scale gaps often necessitates intermediate materials or spacers between the emitter and receiver. Over the past few decades, various spacer designs have been proposed and studied, demonstrating their effectiveness in enhancing energy transfer and conversion. However, challenges remain regarding their reliability and scalability. This article provides a comprehensive overview of spacer technologies for thermionics and thermophotovoltaics and summarizes recent advancements, current capabilities, and persistent challenges.
format Preprint
id arxiv_https___arxiv_org_abs_2503_02732
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Micro/nanoscale spacers for enhanced thermophotovoltaic and thermionic energy conversion: a comprehensive review
Loubet, Nicolas A
Bezdjian, Katie
Lopez, Esther
Datas, Alejandro
Materials Science
Thermionics and thermophotovoltaics are solid-state technologies that convert high-temperature heat into electricity by utilizing fundamental particles, electrons in thermionics and photons in thermophotovoltaics, as energy carriers. Both systems have the potential to achieve high efficiency and power density, contingent on the optimization of radiative/electronic energy fluxes. A critical factor in enhancing energy flux in these devices is the introduction of microscale (thermionics) or nanoscale (thermophotovoltaics) gaps between the hot thermal emitter and the cooler receiver. In thermionic converters, microscale gaps mitigate space charge effects that create energy barriers to electron flow. For thermophotovoltaic systems, nanoscale gaps facilitate photon tunneling, significantly boosting photon flux towards the thermophotovoltaic cell. Forming these small-scale gaps often necessitates intermediate materials or spacers between the emitter and receiver. Over the past few decades, various spacer designs have been proposed and studied, demonstrating their effectiveness in enhancing energy transfer and conversion. However, challenges remain regarding their reliability and scalability. This article provides a comprehensive overview of spacer technologies for thermionics and thermophotovoltaics and summarizes recent advancements, current capabilities, and persistent challenges.
title Micro/nanoscale spacers for enhanced thermophotovoltaic and thermionic energy conversion: a comprehensive review
topic Materials Science
url https://arxiv.org/abs/2503.02732