Nuclear clock based on the Th V ion

Fuente: arXiv
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Main Authors: Dzuba, V. A., Flambaum, V. V., Peik, E.
Format: Preprint
Published: 2025
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author Dzuba, V. A.
Flambaum, V. V.
Peik, E.
author_facet Dzuba, V. A.
Flambaum, V. V.
Peik, E.
contents We propose that a nuclear clock based on the Th V ion can surpass the accuracy of clocks built with other thorium ions. The Th$^{4+}$ ion has a rigid closed-shell core with zero total electron angular momentum, suppressing frequency shifts from black-body radiation and stray external fields that act mainly on electrons. We calculate the energy shift of the nuclear clock transition frequency in $^{229}$Th due to the Coulomb field of atomic electrons and find a relative frequency difference of $2.8 \times 10^{-7}$ between Th IV and Th V - twelve orders of magnitude larger than the projected $10^{-19}$ fractional uncertainty of a nuclear clock. We also perform calculations for Th V energy levels, ionization potential, static polarizability, and the black-body radiation shift of the nuclear line. Additionally, we determine the nuclear transition frequencies in two thorium ions and neutral atom: $ω_N=2,020,406.964(70)$ GHz in Th III, $ω_N=2,020,408.264(100)$ GHz in Th II, and $ω_N=2,020,408.364(100)$ GHz in Th I.
format Preprint
id arxiv_https___arxiv_org_abs_2503_04081
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Nuclear clock based on the Th V ion
Dzuba, V. A.
Flambaum, V. V.
Peik, E.
Atomic Physics
We propose that a nuclear clock based on the Th V ion can surpass the accuracy of clocks built with other thorium ions. The Th$^{4+}$ ion has a rigid closed-shell core with zero total electron angular momentum, suppressing frequency shifts from black-body radiation and stray external fields that act mainly on electrons. We calculate the energy shift of the nuclear clock transition frequency in $^{229}$Th due to the Coulomb field of atomic electrons and find a relative frequency difference of $2.8 \times 10^{-7}$ between Th IV and Th V - twelve orders of magnitude larger than the projected $10^{-19}$ fractional uncertainty of a nuclear clock. We also perform calculations for Th V energy levels, ionization potential, static polarizability, and the black-body radiation shift of the nuclear line. Additionally, we determine the nuclear transition frequencies in two thorium ions and neutral atom: $ω_N=2,020,406.964(70)$ GHz in Th III, $ω_N=2,020,408.264(100)$ GHz in Th II, and $ω_N=2,020,408.364(100)$ GHz in Th I.
title Nuclear clock based on the Th V ion
topic Atomic Physics
url https://arxiv.org/abs/2503.04081