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Main Authors: Fava, Mauro, Romero, Aldo H., Bousquet, Eric
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2503.06782
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author Fava, Mauro
Romero, Aldo H.
Bousquet, Eric
author_facet Fava, Mauro
Romero, Aldo H.
Bousquet, Eric
contents A phase transition can drive the spontaneous emergence of chiral orders in crystals below a critical temperature. However, selecting either a right- or a left-handed phase with the aid of electromagnetic fields is challenging, particularly when intrinsic polar and axial moments are lacking. In this work we show that \textit{purely} chiral phases with opposite handedness, when both deriving from one degenerate instability, are linked by accessible transition states. While these states compete with the chirality under an electromagnetic field, a circularly polarized source can select the handedness of the system. This selection is mediated by a chiral monopole and may further result in a hysteresis process of the gyrotropic properties, namely the optical activity, below the critical temperature. We suggest several materials, among which K$_3$NiO$_2$, as candidates for possible experimental observation.
format Preprint
id arxiv_https___arxiv_org_abs_2503_06782
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Handedness selection and hysteresis of chiral orders in crystals
Fava, Mauro
Romero, Aldo H.
Bousquet, Eric
Materials Science
A phase transition can drive the spontaneous emergence of chiral orders in crystals below a critical temperature. However, selecting either a right- or a left-handed phase with the aid of electromagnetic fields is challenging, particularly when intrinsic polar and axial moments are lacking. In this work we show that \textit{purely} chiral phases with opposite handedness, when both deriving from one degenerate instability, are linked by accessible transition states. While these states compete with the chirality under an electromagnetic field, a circularly polarized source can select the handedness of the system. This selection is mediated by a chiral monopole and may further result in a hysteresis process of the gyrotropic properties, namely the optical activity, below the critical temperature. We suggest several materials, among which K$_3$NiO$_2$, as candidates for possible experimental observation.
title Handedness selection and hysteresis of chiral orders in crystals
topic Materials Science
url https://arxiv.org/abs/2503.06782