Density matrices in quantum field theory: Non-Markovianity, path integrals and master equations

Fuente: arXiv
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Main Authors: Käding, Christian, Pitschmann, Mario
Format: Preprint
Published: 2025
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author Käding, Christian
Pitschmann, Mario
author_facet Käding, Christian
Pitschmann, Mario
contents Density matrices are powerful mathematical tools for the description of closed and open quantum systems. Recently, methods for the direct computation of density matrix elements in scalar quantum field theory were developed based on thermo field dynamics (TFD) and the Schwinger-Keldysh formalism. In this article, we provide a more detailed discussion of these methods and derive expressions for density matrix elements of closed and open systems. At first, we look at closed systems by discussing general solutions to the Schrödinger-like form of the quantum Liouville equations in TFD, showing that the dynamical map is indeed divisible, deriving a path integral-based expression for the density matrix elements in Fock space, and explaining why perturbation theory enables us to use the last even in situations where all initial states in Fock space are occupied. Subsequently, we discuss open systems in the same manner after tracing out environmental degrees of freedom from the solutions for closed systems. We find that, even in a general basis, the dynamical map is not divisible, which renders the dynamics of open systems non-Markovian. Finally, we show how the resulting expressions for open systems can be used to obtain quantum master equations, and comment on the artificiality of time integrals over density matrices that usually appear in many other master equations in the literature but are absent in ours.
format Preprint
id arxiv_https___arxiv_org_abs_2503_08567
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Density matrices in quantum field theory: Non-Markovianity, path integrals and master equations
Käding, Christian
Pitschmann, Mario
High Energy Physics - Theory
High Energy Physics - Phenomenology
Quantum Physics
Density matrices are powerful mathematical tools for the description of closed and open quantum systems. Recently, methods for the direct computation of density matrix elements in scalar quantum field theory were developed based on thermo field dynamics (TFD) and the Schwinger-Keldysh formalism. In this article, we provide a more detailed discussion of these methods and derive expressions for density matrix elements of closed and open systems. At first, we look at closed systems by discussing general solutions to the Schrödinger-like form of the quantum Liouville equations in TFD, showing that the dynamical map is indeed divisible, deriving a path integral-based expression for the density matrix elements in Fock space, and explaining why perturbation theory enables us to use the last even in situations where all initial states in Fock space are occupied. Subsequently, we discuss open systems in the same manner after tracing out environmental degrees of freedom from the solutions for closed systems. We find that, even in a general basis, the dynamical map is not divisible, which renders the dynamics of open systems non-Markovian. Finally, we show how the resulting expressions for open systems can be used to obtain quantum master equations, and comment on the artificiality of time integrals over density matrices that usually appear in many other master equations in the literature but are absent in ours.
title Density matrices in quantum field theory: Non-Markovianity, path integrals and master equations
topic High Energy Physics - Theory
High Energy Physics - Phenomenology
Quantum Physics
url https://arxiv.org/abs/2503.08567