New insight on the phase diagram of the superconducting iron spin ladder BaFe$_2$S$_3$

Fuente: arXiv
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Main Authors: Oubaid, Y., Balédent, V., Fabelo, O., Colin, C. V., Chattopadhyay, S., Elkaim, E., Forget, A., Colson, D., Bounoua, D., Verseils, M., Fertey, P., Foury-Leylekian, P.
Format: Preprint
Published: 2025
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author Oubaid, Y.
Balédent, V.
Fabelo, O.
Colin, C. V.
Chattopadhyay, S.
Elkaim, E.
Forget, A.
Colson, D.
Bounoua, D.
Verseils, M.
Fertey, P.
Foury-Leylekian, P.
author_facet Oubaid, Y.
Balédent, V.
Fabelo, O.
Colin, C. V.
Chattopadhyay, S.
Elkaim, E.
Forget, A.
Colson, D.
Bounoua, D.
Verseils, M.
Fertey, P.
Foury-Leylekian, P.
contents BaFe$_2$S$_3$ and BaFe$_2$Se$_3$ are the only two quasi-one-dimensional iron-based compounds that become superconductors under pressure. Interestingly, these two compounds exhibit different symmetries and properties. While more detailed and recent studies on BaFe$_2$Se$_3$ using single crystals have advanced the filed towards a more universal description of this family, such a study is still lacking for the compound BaFe$_2$S$_3$. Here, we present a detailed study of the crystalline and magnetic structure performed on single crystals using X-ray and neutron diffraction. We demonstrate a polar structure at room temperature within the $Cm2m$ space group, followed by a structural transition at 130 K to the polar $Pb2_1m$ space group. This space group remains unchanged across the magnetic transition at $T_N =95$ K, revealing multiferroic characteristics with a weak magnetoelastic coupling. The determined magnetic structure is monoclinic ($P_am$), with non-collinear magnetic moments, displaying a significant angle of 18$^\circ$ relative to the $a$-axis in the $(a, c)$ plane. This reexamination of the temperature-dependent properties of BaFe$_2$S$_3$ provides new insights into the physics of this system from multiple key perspectives.
format Preprint
id arxiv_https___arxiv_org_abs_2503_10942
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle New insight on the phase diagram of the superconducting iron spin ladder BaFe$_2$S$_3$
Oubaid, Y.
Balédent, V.
Fabelo, O.
Colin, C. V.
Chattopadhyay, S.
Elkaim, E.
Forget, A.
Colson, D.
Bounoua, D.
Verseils, M.
Fertey, P.
Foury-Leylekian, P.
Strongly Correlated Electrons
Superconductivity
BaFe$_2$S$_3$ and BaFe$_2$Se$_3$ are the only two quasi-one-dimensional iron-based compounds that become superconductors under pressure. Interestingly, these two compounds exhibit different symmetries and properties. While more detailed and recent studies on BaFe$_2$Se$_3$ using single crystals have advanced the filed towards a more universal description of this family, such a study is still lacking for the compound BaFe$_2$S$_3$. Here, we present a detailed study of the crystalline and magnetic structure performed on single crystals using X-ray and neutron diffraction. We demonstrate a polar structure at room temperature within the $Cm2m$ space group, followed by a structural transition at 130 K to the polar $Pb2_1m$ space group. This space group remains unchanged across the magnetic transition at $T_N =95$ K, revealing multiferroic characteristics with a weak magnetoelastic coupling. The determined magnetic structure is monoclinic ($P_am$), with non-collinear magnetic moments, displaying a significant angle of 18$^\circ$ relative to the $a$-axis in the $(a, c)$ plane. This reexamination of the temperature-dependent properties of BaFe$_2$S$_3$ provides new insights into the physics of this system from multiple key perspectives.
title New insight on the phase diagram of the superconducting iron spin ladder BaFe$_2$S$_3$
topic Strongly Correlated Electrons
Superconductivity
url https://arxiv.org/abs/2503.10942