Identification of Two Distinct Antiferromagnetic Phases in the Au-Al-Gd Quasicrystal Approximant

Fuente: arXiv
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Main Authors: Labib, Farid, Sugimoto, Takanori, Takakura, Hiroyuki, Ishikawa, Asuka, Tamura, Ryuji
Format: Preprint
Published: 2025
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author Labib, Farid
Sugimoto, Takanori
Takakura, Hiroyuki
Ishikawa, Asuka
Tamura, Ryuji
author_facet Labib, Farid
Sugimoto, Takanori
Takakura, Hiroyuki
Ishikawa, Asuka
Tamura, Ryuji
contents The structural and physical properties of two single-grain Au-Al-Gd 1/1 approximant crystals (ACs) with analyzed compositions Au73.67Al12.24Gd14.09 and Au74.67Al11.35Gd13.98 were thoroughly investigated. The two variants are iso-structural (cubic, space group: Im-3 undergoing sharp antiferromagnetic (AFM) transitions at TN = 9.6 K and TN = 8.3 K, respectively. Specific heat measurements in both samples evidenced sharp jump at TN, associated with the AFM transition, accompanied by broad Schottky-type anomalies at lower temperatures. Strikingly, the two 1/1 ACs exhibited markedly different responses to applied magnetic fields: one displayed a pronounced metamagnetic anomaly while the other did not. In this regard, variational calculations with adiabatic transformation of the magnetic field in realistic structural models identified the existence of two possible AFM phases: the cuboc phase with a metamagnetic anomaly and the cluster Néel phase without it, thereby clearly revealing the possible magnetic structures of the present AFM variants. These findings have led to the establishment of a comprehensive magnetic phase diagram for Heisenberg-type 1/1 ACs. This work not only advances our understanding of magnetic phase transitions in these complex systems but also suggests the existence of a broader spectrum of unexplored magnetic states in Tsai-type materials.
format Preprint
id arxiv_https___arxiv_org_abs_2503_12279
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Identification of Two Distinct Antiferromagnetic Phases in the Au-Al-Gd Quasicrystal Approximant
Labib, Farid
Sugimoto, Takanori
Takakura, Hiroyuki
Ishikawa, Asuka
Tamura, Ryuji
Materials Science
Applied Physics
The structural and physical properties of two single-grain Au-Al-Gd 1/1 approximant crystals (ACs) with analyzed compositions Au73.67Al12.24Gd14.09 and Au74.67Al11.35Gd13.98 were thoroughly investigated. The two variants are iso-structural (cubic, space group: Im-3 undergoing sharp antiferromagnetic (AFM) transitions at TN = 9.6 K and TN = 8.3 K, respectively. Specific heat measurements in both samples evidenced sharp jump at TN, associated with the AFM transition, accompanied by broad Schottky-type anomalies at lower temperatures. Strikingly, the two 1/1 ACs exhibited markedly different responses to applied magnetic fields: one displayed a pronounced metamagnetic anomaly while the other did not. In this regard, variational calculations with adiabatic transformation of the magnetic field in realistic structural models identified the existence of two possible AFM phases: the cuboc phase with a metamagnetic anomaly and the cluster Néel phase without it, thereby clearly revealing the possible magnetic structures of the present AFM variants. These findings have led to the establishment of a comprehensive magnetic phase diagram for Heisenberg-type 1/1 ACs. This work not only advances our understanding of magnetic phase transitions in these complex systems but also suggests the existence of a broader spectrum of unexplored magnetic states in Tsai-type materials.
title Identification of Two Distinct Antiferromagnetic Phases in the Au-Al-Gd Quasicrystal Approximant
topic Materials Science
Applied Physics
url https://arxiv.org/abs/2503.12279