Spiral spin liquid in a frustrated honeycomb antiferromagnet: A single-crystal study of GdZnPO

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Main Authors: Wan, Zongtang, Zhao, Yuqian, Chen, Xun, Ma, Zhaohua, Li, Zikang, Ouyang, Zhongwen, Li, Yuesheng
Format: Preprint
Published: 2025
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author Wan, Zongtang
Zhao, Yuqian
Chen, Xun
Ma, Zhaohua
Li, Zikang
Ouyang, Zhongwen
Li, Yuesheng
author_facet Wan, Zongtang
Zhao, Yuqian
Chen, Xun
Ma, Zhaohua
Li, Zikang
Ouyang, Zhongwen
Li, Yuesheng
contents The frustrated honeycomb spin model can stabilize a subextensively degenerate spiral spin liquid with nontrivial topological excitations and defects, but its material realization remains rare. Here, we report the experimental realization of this model in the structurally disorder-free compound GdZnPO. Using a single-crystal sample, we find that spin-7/2 rare-earth Gd$^{3+}$ ions form a honeycomb lattice with dominant second-nearest-neighbor antiferromagnetic and first-nearest-neighbor ferromagnetic couplings, along with easy-plane single-site anisotropy. This frustrated model stabilizes a unique spiral spin liquid with a degenerate contour around the $\mathrm{K}$$\{$1/3,1/3$\}$ point in reciprocal space, consistent with our experiments down to 30 mK, including the observation of a giant residual specific heat. Our results establish GdZnPO as an ideal platform for exploring the stability of spiral spin liquids and their novel properties, such as the emergence of low-energy topological defects on the sublattices.
format Preprint
id arxiv_https___arxiv_org_abs_2503_12396
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Spiral spin liquid in a frustrated honeycomb antiferromagnet: A single-crystal study of GdZnPO
Wan, Zongtang
Zhao, Yuqian
Chen, Xun
Ma, Zhaohua
Li, Zikang
Ouyang, Zhongwen
Li, Yuesheng
Strongly Correlated Electrons
Materials Science
The frustrated honeycomb spin model can stabilize a subextensively degenerate spiral spin liquid with nontrivial topological excitations and defects, but its material realization remains rare. Here, we report the experimental realization of this model in the structurally disorder-free compound GdZnPO. Using a single-crystal sample, we find that spin-7/2 rare-earth Gd$^{3+}$ ions form a honeycomb lattice with dominant second-nearest-neighbor antiferromagnetic and first-nearest-neighbor ferromagnetic couplings, along with easy-plane single-site anisotropy. This frustrated model stabilizes a unique spiral spin liquid with a degenerate contour around the $\mathrm{K}$$\{$1/3,1/3$\}$ point in reciprocal space, consistent with our experiments down to 30 mK, including the observation of a giant residual specific heat. Our results establish GdZnPO as an ideal platform for exploring the stability of spiral spin liquids and their novel properties, such as the emergence of low-energy topological defects on the sublattices.
title Spiral spin liquid in a frustrated honeycomb antiferromagnet: A single-crystal study of GdZnPO
topic Strongly Correlated Electrons
Materials Science
url https://arxiv.org/abs/2503.12396