Non-equilibrium Capacitance Loss in EDLC Based on Ion Flux
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arXiv
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| Auteurs principaux: | , , |
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| Format: | Preprint |
| Publié: |
2025
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| _version_ | 1866908275894648832 |
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| author | Li, Jia Zhang, Xinyu Wu, Wei |
| author_facet | Li, Jia Zhang, Xinyu Wu, Wei |
| contents | Understanding the loss of non-equilibrium capacitance in the electric double layer capacitor (EDLC) during continuous charging compared to equilibrium capacitance is crucial for the design of high-rate energy storage devices. Due to three major challenges, including strong ion correlations induced by high concentrations at the interface, the difficulty in representing far from equilibrium, and numerical stability issues, current numerical simulations of ion distribution based on statistical mechanics struggle to achieve long-term accurate modeling under realistic parameters. Since non-equilibrium capacitance loss is a universal macroscopic phenomenon in EDLC, which exists independently of the microscopic model of the electrolyte, this study starts from macroscopic non-equilibrium phenomena, introduces a novel perspective centered on ion flux (IF) for the first time. By deriving the relationship among the charging current, IF, and displacement current, a novel capacitance model based on IF is first established. It is further demonstrated that the current relationship and voltage relationship of EDLC, when represented by conventional circuit models, exhibit inherent contradictions. Therefore, a new interpretative framework is proposed, wherein IF and displacement current are analogized to acceleration and deformation in an elastic medium, respectively. Inspired by this insight, this study reveals that the decrease in non-equilibrium capacitance with increasing charging current originates from the inherent resistance of IF to external charging. This tendency to restore equilibrium is the fundamental cause of non-equilibrium capacitance loss. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2503_15565 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Non-equilibrium Capacitance Loss in EDLC Based on Ion Flux Li, Jia Zhang, Xinyu Wu, Wei Materials Science Understanding the loss of non-equilibrium capacitance in the electric double layer capacitor (EDLC) during continuous charging compared to equilibrium capacitance is crucial for the design of high-rate energy storage devices. Due to three major challenges, including strong ion correlations induced by high concentrations at the interface, the difficulty in representing far from equilibrium, and numerical stability issues, current numerical simulations of ion distribution based on statistical mechanics struggle to achieve long-term accurate modeling under realistic parameters. Since non-equilibrium capacitance loss is a universal macroscopic phenomenon in EDLC, which exists independently of the microscopic model of the electrolyte, this study starts from macroscopic non-equilibrium phenomena, introduces a novel perspective centered on ion flux (IF) for the first time. By deriving the relationship among the charging current, IF, and displacement current, a novel capacitance model based on IF is first established. It is further demonstrated that the current relationship and voltage relationship of EDLC, when represented by conventional circuit models, exhibit inherent contradictions. Therefore, a new interpretative framework is proposed, wherein IF and displacement current are analogized to acceleration and deformation in an elastic medium, respectively. Inspired by this insight, this study reveals that the decrease in non-equilibrium capacitance with increasing charging current originates from the inherent resistance of IF to external charging. This tendency to restore equilibrium is the fundamental cause of non-equilibrium capacitance loss. |
| title | Non-equilibrium Capacitance Loss in EDLC Based on Ion Flux |
| topic | Materials Science |
| url | https://arxiv.org/abs/2503.15565 |