Jahn-Teller Effect for Controlling Quantum Correlations in Hexanuclear Fe$^{3+}$ Magnets

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Main Authors: Zad, Hamid Arian, Jaščur, Michal, Ali, Asad, Al-Kuwari, Saif, Haddadi, Saeed
Format: Preprint
Published: 2025
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author Zad, Hamid Arian
Jaščur, Michal
Ali, Asad
Al-Kuwari, Saif
Haddadi, Saeed
author_facet Zad, Hamid Arian
Jaščur, Michal
Ali, Asad
Al-Kuwari, Saif
Haddadi, Saeed
contents We investigate the low-temperature magnetic and quantum properties of hexanuclear Fe$^ {3+}_6$ complexes under an external magnetic field. We primarily study the impact of competing exchange interactions and their asymmetries induced by the Jahn-Teller distortion on the quantum properties of the complexes. The inequality in exchange interactions lifts the ground-state degeneracy that gives rise to complex quantum behavior. By constructing the ground-state phase diagram and analyzing magnetization, we identify key magnetic phases and critical phenomena. We further quantify quantum correlations using tripartite entanglement negativity and conditional von Neumann entropy to unveil how the Jahn-Teller effect enhances intra-triangle entanglement while modulating inter-triangle correlations. Our findings highlight the Fe$^{3+}_6$ complex as a promising molecular platform for tunable quantum correlations, with potential applications in quantum information processing and molecular qubits.
format Preprint
id arxiv_https___arxiv_org_abs_2503_19076
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Jahn-Teller Effect for Controlling Quantum Correlations in Hexanuclear Fe$^{3+}$ Magnets
Zad, Hamid Arian
Jaščur, Michal
Ali, Asad
Al-Kuwari, Saif
Haddadi, Saeed
Materials Science
Quantum Physics
We investigate the low-temperature magnetic and quantum properties of hexanuclear Fe$^ {3+}_6$ complexes under an external magnetic field. We primarily study the impact of competing exchange interactions and their asymmetries induced by the Jahn-Teller distortion on the quantum properties of the complexes. The inequality in exchange interactions lifts the ground-state degeneracy that gives rise to complex quantum behavior. By constructing the ground-state phase diagram and analyzing magnetization, we identify key magnetic phases and critical phenomena. We further quantify quantum correlations using tripartite entanglement negativity and conditional von Neumann entropy to unveil how the Jahn-Teller effect enhances intra-triangle entanglement while modulating inter-triangle correlations. Our findings highlight the Fe$^{3+}_6$ complex as a promising molecular platform for tunable quantum correlations, with potential applications in quantum information processing and molecular qubits.
title Jahn-Teller Effect for Controlling Quantum Correlations in Hexanuclear Fe$^{3+}$ Magnets
topic Materials Science
Quantum Physics
url https://arxiv.org/abs/2503.19076