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Main Authors: Domínguez-Vázquez, José María, Caballero-Calero, Olga, Lohani, Ketan, Plata, José J., Marquez, Antonio M., Manzano, Cristina V., Tenaguillo, Miguel Ángel, Ohta, Hiromichi, Cebollada, Alfonso, Conca, Andres, Martín-González, Marisol
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2503.21575
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author Domínguez-Vázquez, José María
Caballero-Calero, Olga
Lohani, Ketan
Plata, José J.
Marquez, Antonio M.
Manzano, Cristina V.
Tenaguillo, Miguel Ángel
Ohta, Hiromichi
Cebollada, Alfonso
Conca, Andres
Martín-González, Marisol
author_facet Domínguez-Vázquez, José María
Caballero-Calero, Olga
Lohani, Ketan
Plata, José J.
Marquez, Antonio M.
Manzano, Cristina V.
Tenaguillo, Miguel Ángel
Ohta, Hiromichi
Cebollada, Alfonso
Conca, Andres
Martín-González, Marisol
contents This study demonstrates the direct correlation between the presence of the L2$_1$ ordered phase and the large enhancement in the thermoelectric performance of Fe$_2$VAl thin films deposited on MgO and Al$_2$O$_3$ substrates at temperatures varying between room temperature and 950$^{\circ}$C. We employ both experimental techniques and computational modeling to analyze the influence of crystallographic orientation and deposition temperature on the thermoelectric properties, including the Seebeck coefficient, electrical conductivity, and thermal conductivity. Our findings indicate that the presence of the L2$_1$ phase significantly enhances the power factor (PF) and figure of merit (zT), surpassing previously reported values for both bulk and thin film forms of Fe$_2$VAl, achieving a PF of 480 $μ$W/m$\cdot$K$^2$ and a zT of 0.025.
format Preprint
id arxiv_https___arxiv_org_abs_2503_21575
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Thermoelectric Performance Boost by Chemical Order in Epitaxial L2$_1$ (100) and (110) Oriented undoped Fe$_2$VAl Thin Films: An Experimental and Theoretical Study
Domínguez-Vázquez, José María
Caballero-Calero, Olga
Lohani, Ketan
Plata, José J.
Marquez, Antonio M.
Manzano, Cristina V.
Tenaguillo, Miguel Ángel
Ohta, Hiromichi
Cebollada, Alfonso
Conca, Andres
Martín-González, Marisol
Materials Science
This study demonstrates the direct correlation between the presence of the L2$_1$ ordered phase and the large enhancement in the thermoelectric performance of Fe$_2$VAl thin films deposited on MgO and Al$_2$O$_3$ substrates at temperatures varying between room temperature and 950$^{\circ}$C. We employ both experimental techniques and computational modeling to analyze the influence of crystallographic orientation and deposition temperature on the thermoelectric properties, including the Seebeck coefficient, electrical conductivity, and thermal conductivity. Our findings indicate that the presence of the L2$_1$ phase significantly enhances the power factor (PF) and figure of merit (zT), surpassing previously reported values for both bulk and thin film forms of Fe$_2$VAl, achieving a PF of 480 $μ$W/m$\cdot$K$^2$ and a zT of 0.025.
title Thermoelectric Performance Boost by Chemical Order in Epitaxial L2$_1$ (100) and (110) Oriented undoped Fe$_2$VAl Thin Films: An Experimental and Theoretical Study
topic Materials Science
url https://arxiv.org/abs/2503.21575