Chemical enhancement of superconductivity in LaRu3Si2 with mode-selective coupling between kagome phonons and flat bands

Fuente: arXiv
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Main Authors: Misawa, Ryo, Kriener, Markus, Yamada, Rinsuke, Nakano, Ryota, Jovanovic, Milena, Schoop, Leslie M., Hirschberger, Max
Format: Preprint
Published: 2025
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author Misawa, Ryo
Kriener, Markus
Yamada, Rinsuke
Nakano, Ryota
Jovanovic, Milena
Schoop, Leslie M.
Hirschberger, Max
author_facet Misawa, Ryo
Kriener, Markus
Yamada, Rinsuke
Nakano, Ryota
Jovanovic, Milena
Schoop, Leslie M.
Hirschberger, Max
contents In kagome metals, flat electronic bands induced by frustrated hopping are a platform for strong electron correlations. In particular, a selective coupling of flat band states to certain kagome phonon modes is proposed as a universal origin of superconductivity in this material class. Here, we investigate the superconductivity in the kagome system LaRu$_3$(Si$_{1-x}$Ge$_x$)$_2$ by chemical pressure tuning while preserving the Ru-$4d$ states that constitute the kagome flat bands. We observe a sizable enhancement in the density of states up to $x = 0.07$, as determined by the specific heat, with a concomitant increase in the superconducting transition temperature $T_\mathrm{c}$. Ge-dopants induce a uniaxial lattice expansion along the $c$-axis. Our first-principles calculations suggest that this mitigates the detrimental effect of hybridization between kagome layers and reduces the dispersion of the Ru-$4d_{x^2-y^2}$ flat band. The calculated chemical potential moves closer to the maximum in the energy-dependent density of states. Our result is consistent with a theoretical prediction of tunable flat band superconductivity in LaRu$_3$Si$_2$ by mode-selective coupling between specific kagome phonons and the Ru-$d_{x^2-y^2}$ orbitals.
format Preprint
id arxiv_https___arxiv_org_abs_2503_22477
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Chemical enhancement of superconductivity in LaRu3Si2 with mode-selective coupling between kagome phonons and flat bands
Misawa, Ryo
Kriener, Markus
Yamada, Rinsuke
Nakano, Ryota
Jovanovic, Milena
Schoop, Leslie M.
Hirschberger, Max
Superconductivity
Materials Science
Strongly Correlated Electrons
In kagome metals, flat electronic bands induced by frustrated hopping are a platform for strong electron correlations. In particular, a selective coupling of flat band states to certain kagome phonon modes is proposed as a universal origin of superconductivity in this material class. Here, we investigate the superconductivity in the kagome system LaRu$_3$(Si$_{1-x}$Ge$_x$)$_2$ by chemical pressure tuning while preserving the Ru-$4d$ states that constitute the kagome flat bands. We observe a sizable enhancement in the density of states up to $x = 0.07$, as determined by the specific heat, with a concomitant increase in the superconducting transition temperature $T_\mathrm{c}$. Ge-dopants induce a uniaxial lattice expansion along the $c$-axis. Our first-principles calculations suggest that this mitigates the detrimental effect of hybridization between kagome layers and reduces the dispersion of the Ru-$4d_{x^2-y^2}$ flat band. The calculated chemical potential moves closer to the maximum in the energy-dependent density of states. Our result is consistent with a theoretical prediction of tunable flat band superconductivity in LaRu$_3$Si$_2$ by mode-selective coupling between specific kagome phonons and the Ru-$d_{x^2-y^2}$ orbitals.
title Chemical enhancement of superconductivity in LaRu3Si2 with mode-selective coupling between kagome phonons and flat bands
topic Superconductivity
Materials Science
Strongly Correlated Electrons
url https://arxiv.org/abs/2503.22477