Vapor-mediated wetting and imbibition control on micropatterned surfaces

Fuente: arXiv
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Autores principales: Xu, Ze, Saiseau, Raphael, Soto, Olinka Ramírez, Karpitschka, Stefan
Formato: Preprint
Publicado: 2025
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author Xu, Ze
Saiseau, Raphael
Soto, Olinka Ramírez
Karpitschka, Stefan
author_facet Xu, Ze
Saiseau, Raphael
Soto, Olinka Ramírez
Karpitschka, Stefan
contents Wetting of micropatterned surfaces is ubiquitous in nature and key to many technological applications like spray cooling, inkjet printing, and semiconductor processing. Overcoming the intrinsic, chemistry- and topography-governed wetting behaviors often requires specific materials which limits applicability. Here, we show that spreading and wicking of water droplets on hydrophilic surface patterns can be controlled by the presence of the vapor of another liquid with lower surface tension. We show that delayed wicking arises from Marangoni forces due to vapor condensation, competing with the capillary wicking force of the surface topography. Thereby, macroscopic droplets can be brought into an effective apparent wetting behavior, decoupled from the surface topography, but coexisting with a wicking film, cloaking the pattern. We demonstrate how modulating the vapor concentration in space and time may guide droplets across patterns and even extract imbibed liquids, devising new strategies for coating, cleaning and drying of functional surface designs.
format Preprint
id arxiv_https___arxiv_org_abs_2503_23699
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Vapor-mediated wetting and imbibition control on micropatterned surfaces
Xu, Ze
Saiseau, Raphael
Soto, Olinka Ramírez
Karpitschka, Stefan
Soft Condensed Matter
Fluid Dynamics
Wetting of micropatterned surfaces is ubiquitous in nature and key to many technological applications like spray cooling, inkjet printing, and semiconductor processing. Overcoming the intrinsic, chemistry- and topography-governed wetting behaviors often requires specific materials which limits applicability. Here, we show that spreading and wicking of water droplets on hydrophilic surface patterns can be controlled by the presence of the vapor of another liquid with lower surface tension. We show that delayed wicking arises from Marangoni forces due to vapor condensation, competing with the capillary wicking force of the surface topography. Thereby, macroscopic droplets can be brought into an effective apparent wetting behavior, decoupled from the surface topography, but coexisting with a wicking film, cloaking the pattern. We demonstrate how modulating the vapor concentration in space and time may guide droplets across patterns and even extract imbibed liquids, devising new strategies for coating, cleaning and drying of functional surface designs.
title Vapor-mediated wetting and imbibition control on micropatterned surfaces
topic Soft Condensed Matter
Fluid Dynamics
url https://arxiv.org/abs/2503.23699