Bismuth plasmonic antennas

Fuente: arXiv
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Autori principali: Foltýn, Michael, Šikola, Tomáš, Horák, Michal
Natura: Preprint
Pubblicazione: 2025
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author Foltýn, Michael
Šikola, Tomáš
Horák, Michal
author_facet Foltýn, Michael
Šikola, Tomáš
Horák, Michal
contents Bismuth is a particularly promising alternative plasmonic metal because of its theoretically predicted wide spectral bandwidth. In this study, we experimentally demonstrated the correlation between the shape and size of individual bismuth plasmonic antennas and their optical properties. To this end, we employed a combination of scanning transmission electron microscopy and electron energy loss spectroscopy. Bar-shaped and bowtie bismuth plasmonic antennas of various sizes were fabricated by focused ion beam lithography of a polycrystalline bismuth thin film. Our experimental findings demonstrate that these antennas support localised surface plasmon resonances and their dipole modes can be tuned through their size from the near-infrared to the entire visible spectral region. Furthermore, our findings demonstrate that bismuth exhibits a plasmon dispersion relation that is nearly identical to that of gold while maintaining its plasmonic performance even at higher plasmon energies, thus rendering it a promising low-cost alternative to gold.
format Preprint
id arxiv_https___arxiv_org_abs_2504_00671
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Bismuth plasmonic antennas
Foltýn, Michael
Šikola, Tomáš
Horák, Michal
Optics
Mesoscale and Nanoscale Physics
Bismuth is a particularly promising alternative plasmonic metal because of its theoretically predicted wide spectral bandwidth. In this study, we experimentally demonstrated the correlation between the shape and size of individual bismuth plasmonic antennas and their optical properties. To this end, we employed a combination of scanning transmission electron microscopy and electron energy loss spectroscopy. Bar-shaped and bowtie bismuth plasmonic antennas of various sizes were fabricated by focused ion beam lithography of a polycrystalline bismuth thin film. Our experimental findings demonstrate that these antennas support localised surface plasmon resonances and their dipole modes can be tuned through their size from the near-infrared to the entire visible spectral region. Furthermore, our findings demonstrate that bismuth exhibits a plasmon dispersion relation that is nearly identical to that of gold while maintaining its plasmonic performance even at higher plasmon energies, thus rendering it a promising low-cost alternative to gold.
title Bismuth plasmonic antennas
topic Optics
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2504.00671