Weak Itinerant Ferromagnetism (WIFM) in MAX phase compound Cr$_{1.9}$Fe$_{0.1}$GeC

Fuente: arXiv
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Autori principali: Mondal, Suman, Numan, Mohamad, Kummer, Kurt, Masahiro, Sawada, Majumdar, Subham
Natura: Preprint
Pubblicazione: 2025
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author Mondal, Suman
Numan, Mohamad
Kummer, Kurt
Masahiro, Sawada
Majumdar, Subham
author_facet Mondal, Suman
Numan, Mohamad
Kummer, Kurt
Masahiro, Sawada
Majumdar, Subham
contents Magnetic MAX phase compounds are important materials for studying the two-dimensional magnetism because of their layered crystallographic structure. The hexagonal MAX phase compound Cr$_2$GeC is a Pauli paramagnet, and here we report the induction of an ordered magnetic state by doping Fe at the Cr site. Induced magnetism for small doping concentrations (indicated as 5% and 2.5%) is found to have a weak itinerant ferromagnetic character. The Rhodes-Wolhfarth ratio is found to be 13.29, while the coefficient of electronic heat capacity ($Γ$) is 27 mJ-mol$^{-1}$K$^{-2}$ for Cr$_{1.9}$Fe$_{0.1}$GeC. Our x-ray magnetic circular dichorism measurement confirms that the magnetic moment arises from the Fe atom only, and Cr has negligible contribution towards the ordered moment. Our critical analysis indicates that the magnetic phase transition in Cr$_{1.9}$Fe$_{0.1}$GeC follows mean field theory.
format Preprint
id arxiv_https___arxiv_org_abs_2504_02378
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Weak Itinerant Ferromagnetism (WIFM) in MAX phase compound Cr$_{1.9}$Fe$_{0.1}$GeC
Mondal, Suman
Numan, Mohamad
Kummer, Kurt
Masahiro, Sawada
Majumdar, Subham
Strongly Correlated Electrons
Magnetic MAX phase compounds are important materials for studying the two-dimensional magnetism because of their layered crystallographic structure. The hexagonal MAX phase compound Cr$_2$GeC is a Pauli paramagnet, and here we report the induction of an ordered magnetic state by doping Fe at the Cr site. Induced magnetism for small doping concentrations (indicated as 5% and 2.5%) is found to have a weak itinerant ferromagnetic character. The Rhodes-Wolhfarth ratio is found to be 13.29, while the coefficient of electronic heat capacity ($Γ$) is 27 mJ-mol$^{-1}$K$^{-2}$ for Cr$_{1.9}$Fe$_{0.1}$GeC. Our x-ray magnetic circular dichorism measurement confirms that the magnetic moment arises from the Fe atom only, and Cr has negligible contribution towards the ordered moment. Our critical analysis indicates that the magnetic phase transition in Cr$_{1.9}$Fe$_{0.1}$GeC follows mean field theory.
title Weak Itinerant Ferromagnetism (WIFM) in MAX phase compound Cr$_{1.9}$Fe$_{0.1}$GeC
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2504.02378