Superconductivity in the Medium-Entropy/High-Entropy Re-based Alloys with a Non-Centrosymmetric $α$-Mn Lattice

Fuente: arXiv
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Autores principales: Li, Kuan, Li, Longfu, Zenga, Lingyong, Li, Yucheng, Chen, Rui, Yu, Peifeng, Wang, Kangwang, Xiang, Zaichen, Shang, Tian, Luo, Huixia
Formato: Preprint
Publicado: 2025
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author Li, Kuan
Li, Longfu
Zenga, Lingyong
Li, Yucheng
Chen, Rui
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Shang, Tian
Luo, Huixia
author_facet Li, Kuan
Li, Longfu
Zenga, Lingyong
Li, Yucheng
Chen, Rui
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Shang, Tian
Luo, Huixia
contents Medium or high-entropy alloys (MEAs-HEAs) and rhenium-based compounds with a non-centrosymmetric (NC) structure have received a lot of attention for offering a fertile soil in search for unconventional superconductivity. Here, five previously unreported NC Re-based MEA-HEA superconductors with an $α$-Mn lattice are successfully synthesized, with their superconducting transition temperatures (Tcs) ranging from 4 to 5 K. An increase in the superconducting transition temperature (Tc) can be achieved by modulating the valence electron count (VEC) through compositional adjustments. Magnetization measurements confirm that all the synthesized Re-based MEA-HEAs are bulk type-II superconductors. Specific heat analysis reveals that the superconducting state of these HEAs can be well described by a single-gap s-wave model. Our results show that the Kadowaki-Woods ratio of these $α$-Mn MEA/HEA superconductors are close to the typical value of heavy fermion compounds, suggesting the existence of strong electronic correlation. These findings provide promising material platforms to study the role of high disorder in the origin of superconductivity in the NC MEAs-HEAs.
format Preprint
id arxiv_https___arxiv_org_abs_2504_02556
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Superconductivity in the Medium-Entropy/High-Entropy Re-based Alloys with a Non-Centrosymmetric $α$-Mn Lattice
Li, Kuan
Li, Longfu
Zenga, Lingyong
Li, Yucheng
Chen, Rui
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Shang, Tian
Luo, Huixia
Superconductivity
Medium or high-entropy alloys (MEAs-HEAs) and rhenium-based compounds with a non-centrosymmetric (NC) structure have received a lot of attention for offering a fertile soil in search for unconventional superconductivity. Here, five previously unreported NC Re-based MEA-HEA superconductors with an $α$-Mn lattice are successfully synthesized, with their superconducting transition temperatures (Tcs) ranging from 4 to 5 K. An increase in the superconducting transition temperature (Tc) can be achieved by modulating the valence electron count (VEC) through compositional adjustments. Magnetization measurements confirm that all the synthesized Re-based MEA-HEAs are bulk type-II superconductors. Specific heat analysis reveals that the superconducting state of these HEAs can be well described by a single-gap s-wave model. Our results show that the Kadowaki-Woods ratio of these $α$-Mn MEA/HEA superconductors are close to the typical value of heavy fermion compounds, suggesting the existence of strong electronic correlation. These findings provide promising material platforms to study the role of high disorder in the origin of superconductivity in the NC MEAs-HEAs.
title Superconductivity in the Medium-Entropy/High-Entropy Re-based Alloys with a Non-Centrosymmetric $α$-Mn Lattice
topic Superconductivity
url https://arxiv.org/abs/2504.02556