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Bibliographische Detailangaben
Hauptverfasser: Chuiko, Valerii, Da Rosa, Giovanni B., Ayers, Paul W.
Format: Preprint
Veröffentlicht: 2025
Schlagworte:
Online-Zugang:https://arxiv.org/abs/2504.03849
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Inhaltsangabe:
  • We propose a descriptor for molecular electronic structure that is based solely on the one- and two-electron integrals but is translationally, rotationally, and unitarily invariant. Then, directly exploiting size consistency, we train and fine tune a neural network to predict the energies of strongly-correlated systems, specifically hydrogen clusters. We use an attention mechanism to formulate a size-independent approach that uses and preserves size-consistency. Therefore, training on few-electron systems can guide predictions for systems with more electrons. Our results are more accurate than alternative geometry-based machine-learning models.