Ultrafast dynamics of vibronically dressed core-excitons in graphite: a femtosecond RIXS perspective

Fuente: arXiv
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Main Authors: Malvestuto, Marco, Volpato, Beatrice, Babici, Elena, Bhardwaj, Richa, Caretta, Antonio, Laterza, Simone, Parmigiani, Fulvio, Manfredda, Michele, Simoncig, Alberto, Zangrando, Marco, Demidovich, Alexander, Susnjar, Peter, Allaria, Enrico Massimiliano, Brynes, Alexander Darius, Garzella, David, Giannessi, Luca, Rebernik, Primoz, Sottocorona, Filippo, Novko, Dino
Format: Preprint
Published: 2025
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author Malvestuto, Marco
Volpato, Beatrice
Babici, Elena
Bhardwaj, Richa
Caretta, Antonio
Laterza, Simone
Parmigiani, Fulvio
Manfredda, Michele
Simoncig, Alberto
Zangrando, Marco
Demidovich, Alexander
Susnjar, Peter
Allaria, Enrico Massimiliano
Brynes, Alexander Darius
Garzella, David
Giannessi, Luca
Rebernik, Primoz
Sottocorona, Filippo
Novko, Dino
author_facet Malvestuto, Marco
Volpato, Beatrice
Babici, Elena
Bhardwaj, Richa
Caretta, Antonio
Laterza, Simone
Parmigiani, Fulvio
Manfredda, Michele
Simoncig, Alberto
Zangrando, Marco
Demidovich, Alexander
Susnjar, Peter
Allaria, Enrico Massimiliano
Brynes, Alexander Darius
Garzella, David
Giannessi, Luca
Rebernik, Primoz
Sottocorona, Filippo
Novko, Dino
contents This study demonstrates one of the first implementations of time-resolved resonant inelastic X-ray scattering (tr-RIXS), marking a seminal extension of RIXS spectroscopy into the ultrafast time domain. By investigating the ultrafast dynamics of vibronically dressed core excitons in graphite using femtosecond X-ray pulses from a Free Electron Laser, we reveal previously inaccessible insights into the transient coupling between core excitons and specific optical phonon modes. Our approach establishes tr-RIXS as a powerful, transformative tool capable of elucidating the intricate interplay between electronic and lattice dynamics, opening new avenues in ultrafast materials research.
format Preprint
id arxiv_https___arxiv_org_abs_2504_12708
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Ultrafast dynamics of vibronically dressed core-excitons in graphite: a femtosecond RIXS perspective
Malvestuto, Marco
Volpato, Beatrice
Babici, Elena
Bhardwaj, Richa
Caretta, Antonio
Laterza, Simone
Parmigiani, Fulvio
Manfredda, Michele
Simoncig, Alberto
Zangrando, Marco
Demidovich, Alexander
Susnjar, Peter
Allaria, Enrico Massimiliano
Brynes, Alexander Darius
Garzella, David
Giannessi, Luca
Rebernik, Primoz
Sottocorona, Filippo
Novko, Dino
Materials Science
This study demonstrates one of the first implementations of time-resolved resonant inelastic X-ray scattering (tr-RIXS), marking a seminal extension of RIXS spectroscopy into the ultrafast time domain. By investigating the ultrafast dynamics of vibronically dressed core excitons in graphite using femtosecond X-ray pulses from a Free Electron Laser, we reveal previously inaccessible insights into the transient coupling between core excitons and specific optical phonon modes. Our approach establishes tr-RIXS as a powerful, transformative tool capable of elucidating the intricate interplay between electronic and lattice dynamics, opening new avenues in ultrafast materials research.
title Ultrafast dynamics of vibronically dressed core-excitons in graphite: a femtosecond RIXS perspective
topic Materials Science
url https://arxiv.org/abs/2504.12708