Hardware Implementation of Tunable Fractional-Order Capacitors by Morphogenesis of Conducting Polymer Dendrites

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Hauptverfasser: Baron, Antoine, Balaguera, Enrique H., Scholaert, Corentin, Alibart, Fabien, Pecqueur, Sébastien
Format: Preprint
Veröffentlicht: 2025
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author Baron, Antoine
Balaguera, Enrique H.
Scholaert, Corentin
Alibart, Fabien
Pecqueur, Sébastien
author_facet Baron, Antoine
Balaguera, Enrique H.
Scholaert, Corentin
Alibart, Fabien
Pecqueur, Sébastien
contents Conventional electronics is founded on a paradigm where shaping perfect electrical elements is done at the fabrication plant, so as to make devices and systems identical, "eternally immutable". In nature, morphogenic evolutions are observed in most living organisms and exploit topological plasticity as a low-resource mechanism for in operando manufacturing and computation. Often fractal, the resulting topologies feature inherent disorder: a property which is never exploited in conventional electronics manufacturing, while necessary for data generation and security in software. In this study, we present how such properties can be exploited to implement long-term and evolvable synaptic plasticity in an electronic hardware. The rich topology of conducting polymer dendrites (CPDs) is exploited to program the non-ideality of their electrochemical capacitances containing constant-phase-elements. Their evolution through structural changes alters the characteristic time constants for them to charge and discharge with the applied voltage stimuli. Under a train of voltage spikes, the evolvable current relaxation of the electrochemical systems promotes short-term plasticity with timescales ranging from milliseconds to seconds. This large window depends on the temporality of the voltage pulses used for reading, but also on the structure of a pair of CPDs on two electrodes, grown by voltage pulses. This study demonstrates how relevant physically transient and non-ideal electrochemical components can be exploited for unconventional electronics, with the aim to mimic a universal property of living organisms which could barely be replicated in a silicon monocrystal.
format Preprint
id arxiv_https___arxiv_org_abs_2504_12861
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Hardware Implementation of Tunable Fractional-Order Capacitors by Morphogenesis of Conducting Polymer Dendrites
Baron, Antoine
Balaguera, Enrique H.
Scholaert, Corentin
Alibart, Fabien
Pecqueur, Sébastien
Applied Physics
Conventional electronics is founded on a paradigm where shaping perfect electrical elements is done at the fabrication plant, so as to make devices and systems identical, "eternally immutable". In nature, morphogenic evolutions are observed in most living organisms and exploit topological plasticity as a low-resource mechanism for in operando manufacturing and computation. Often fractal, the resulting topologies feature inherent disorder: a property which is never exploited in conventional electronics manufacturing, while necessary for data generation and security in software. In this study, we present how such properties can be exploited to implement long-term and evolvable synaptic plasticity in an electronic hardware. The rich topology of conducting polymer dendrites (CPDs) is exploited to program the non-ideality of their electrochemical capacitances containing constant-phase-elements. Their evolution through structural changes alters the characteristic time constants for them to charge and discharge with the applied voltage stimuli. Under a train of voltage spikes, the evolvable current relaxation of the electrochemical systems promotes short-term plasticity with timescales ranging from milliseconds to seconds. This large window depends on the temporality of the voltage pulses used for reading, but also on the structure of a pair of CPDs on two electrodes, grown by voltage pulses. This study demonstrates how relevant physically transient and non-ideal electrochemical components can be exploited for unconventional electronics, with the aim to mimic a universal property of living organisms which could barely be replicated in a silicon monocrystal.
title Hardware Implementation of Tunable Fractional-Order Capacitors by Morphogenesis of Conducting Polymer Dendrites
topic Applied Physics
url https://arxiv.org/abs/2504.12861