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Main Authors: Ghosh, Swarnava, Eisenbach, Markus
Format: Preprint
Published: 2025
Subjects:
Online Access:https://arxiv.org/abs/2504.15433
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author Ghosh, Swarnava
Eisenbach, Markus
author_facet Ghosh, Swarnava
Eisenbach, Markus
contents Silicon quantum dots are nanomaterials that are attractive candidates for photovoltaic applications. Doping of these materials creates p-n junctions and is important for solar cells. In this work, we present a first-principles study of the coupled influence of doping and strain on the stability, energy gap, Fermi level, electronic density, and density of states of hydrogen-passivated silicon quantum dots. We find that the cohesive energy and the energy gap decrease with increasing quantum dot size and are strongly influenced by strain. Furthermore, the response to strain also depends on the size of the quantum dot and dopant type. We present expressions of cohesive energy and energy gap as power-law of size and polynomial dependence on strain. We also show that the Fermi energy increases with size for pristine and p-type doping but decreases with size for n-type doping. We also discuss the influence of strain and dopant type on the density of states and electron density of the quantum dots.
format Preprint
id arxiv_https___arxiv_org_abs_2504_15433
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Strain engineering of doped hydrogen passivated silicon quantum dots
Ghosh, Swarnava
Eisenbach, Markus
Materials Science
Silicon quantum dots are nanomaterials that are attractive candidates for photovoltaic applications. Doping of these materials creates p-n junctions and is important for solar cells. In this work, we present a first-principles study of the coupled influence of doping and strain on the stability, energy gap, Fermi level, electronic density, and density of states of hydrogen-passivated silicon quantum dots. We find that the cohesive energy and the energy gap decrease with increasing quantum dot size and are strongly influenced by strain. Furthermore, the response to strain also depends on the size of the quantum dot and dopant type. We present expressions of cohesive energy and energy gap as power-law of size and polynomial dependence on strain. We also show that the Fermi energy increases with size for pristine and p-type doping but decreases with size for n-type doping. We also discuss the influence of strain and dopant type on the density of states and electron density of the quantum dots.
title Strain engineering of doped hydrogen passivated silicon quantum dots
topic Materials Science
url https://arxiv.org/abs/2504.15433