New self-organized benzo[b]thiophene-based materials for GHz applications

Fuente: arXiv
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Hauptverfasser: Mieczkowska, Agnieszka, Herman, Jakub, Rychlowicz, Natan, Zajac, Monika, Harmata, Piotr
Format: Preprint
Veröffentlicht: 2025
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author Mieczkowska, Agnieszka
Herman, Jakub
Rychlowicz, Natan
Zajac, Monika
Harmata, Piotr
author_facet Mieczkowska, Agnieszka
Herman, Jakub
Rychlowicz, Natan
Zajac, Monika
Harmata, Piotr
contents This research delves into the synthesis and characterization of novel liquid crystal compounds derived from benzo[b]Ithiophene cores, focusing on their potential applications in microwave technology. Two synthetic strategies were developed to construct rigid cores, resulting in the successful synthesis of ten compounds with varied terminal groups and lateral substituents. Correlations between molecular structure and mesomorphic properties were elucidated through extensive comparative analysis. Birefringence measurements and quantum chemical calculations further provided insights into the optical properties and polarizability anisotropy of the synthesized compounds. The results highlight the influence of structural diversity on the compounds' suitability for microwave applications. Specifically, compounds featuring carbon-carbon triple bonds and polar terminal groups demonstrated enhanced birefringence and polarizability values, indicating their potential in microwave device fabrication. This study underscores the importance of molecular design in optimizing liquid crystal materials for advanced technological applications.
format Preprint
id arxiv_https___arxiv_org_abs_2504_17499
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle New self-organized benzo[b]thiophene-based materials for GHz applications
Mieczkowska, Agnieszka
Herman, Jakub
Rychlowicz, Natan
Zajac, Monika
Harmata, Piotr
Soft Condensed Matter
Materials Science
This research delves into the synthesis and characterization of novel liquid crystal compounds derived from benzo[b]Ithiophene cores, focusing on their potential applications in microwave technology. Two synthetic strategies were developed to construct rigid cores, resulting in the successful synthesis of ten compounds with varied terminal groups and lateral substituents. Correlations between molecular structure and mesomorphic properties were elucidated through extensive comparative analysis. Birefringence measurements and quantum chemical calculations further provided insights into the optical properties and polarizability anisotropy of the synthesized compounds. The results highlight the influence of structural diversity on the compounds' suitability for microwave applications. Specifically, compounds featuring carbon-carbon triple bonds and polar terminal groups demonstrated enhanced birefringence and polarizability values, indicating their potential in microwave device fabrication. This study underscores the importance of molecular design in optimizing liquid crystal materials for advanced technological applications.
title New self-organized benzo[b]thiophene-based materials for GHz applications
topic Soft Condensed Matter
Materials Science
url https://arxiv.org/abs/2504.17499