The specific heat anomaly stems from a third-order phase transition in the 2D lattice sine-Gordon model
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arXiv
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| Format: | Preprint |
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2025
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| _version_ | 1866908343123050496 |
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| author | Di Cairano, Loris Tkatchenko, Alexandre |
| author_facet | Di Cairano, Loris Tkatchenko, Alexandre |
| contents | The specific heat anomaly (SHA) is broadly observed in statistical mechanics, appearing as a smooth, system-size-independent peak in the specific heat, in contrast to the singular behavior typical of second-order phase transitions (PTs). Its origin remains heavily debated: some attribute it to finite-size effects, others to unidentified phase transitions. Here we investigate SHA using the two-dimensional sine-Gordon (2D-sG) model and microcanonical inflection point analysis (MIPA), uncovering two key results. First, we show that the roughening transition in the 2D-sG model is a genuine third-order PT under MIPA, where the standard thermodynamic quantities remain continuous. This clarifies the ambiguity in the literature, where this transition was often, though inconclusively, attributed to a Berezinskii-Kosterlitz-Thouless (BKT) transition. Through the use of MIPA and a comprehensive analysis of standard thermodynamic observables, we provide a coherent thermodynamic characterization that redefines the nature of this transition. Second, we find that the SHA is not itself a PT but rather the thermodynamic fingerprint of this third-order transition. These findings clarify the nature of SHA within the 2D-sG model and suggest that similar anomalies in other systems, such as the XY model, may likewise originate from third-order PTs, rather than mere crossovers. Our results provide a consistent thermodynamic interpretation of the SHA and highlight the broader relevance of third-order transitions in systems previously thought to exhibit only low-order or crossover transition. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2504_20766 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | The specific heat anomaly stems from a third-order phase transition in the 2D lattice sine-Gordon model Di Cairano, Loris Tkatchenko, Alexandre Statistical Mechanics The specific heat anomaly (SHA) is broadly observed in statistical mechanics, appearing as a smooth, system-size-independent peak in the specific heat, in contrast to the singular behavior typical of second-order phase transitions (PTs). Its origin remains heavily debated: some attribute it to finite-size effects, others to unidentified phase transitions. Here we investigate SHA using the two-dimensional sine-Gordon (2D-sG) model and microcanonical inflection point analysis (MIPA), uncovering two key results. First, we show that the roughening transition in the 2D-sG model is a genuine third-order PT under MIPA, where the standard thermodynamic quantities remain continuous. This clarifies the ambiguity in the literature, where this transition was often, though inconclusively, attributed to a Berezinskii-Kosterlitz-Thouless (BKT) transition. Through the use of MIPA and a comprehensive analysis of standard thermodynamic observables, we provide a coherent thermodynamic characterization that redefines the nature of this transition. Second, we find that the SHA is not itself a PT but rather the thermodynamic fingerprint of this third-order transition. These findings clarify the nature of SHA within the 2D-sG model and suggest that similar anomalies in other systems, such as the XY model, may likewise originate from third-order PTs, rather than mere crossovers. Our results provide a consistent thermodynamic interpretation of the SHA and highlight the broader relevance of third-order transitions in systems previously thought to exhibit only low-order or crossover transition. |
| title | The specific heat anomaly stems from a third-order phase transition in the 2D lattice sine-Gordon model |
| topic | Statistical Mechanics |
| url | https://arxiv.org/abs/2504.20766 |